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Key equations

  • c = λν
  • E = h ν = h c λ , where h = 6.626 × 10 −34 J s
  • 1 λ = R ( 1 n 1 2 1 n 2 2 )

Chemistry end of chapter exercises

The light produced by a red neon sign is due to the emission of light by excited neon atoms. Qualitatively describe the spectrum produced by passing light from a neon lamp through a prism.

The spectrum consists of colored lines, at least one of which (probably the brightest) is red.

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An FM radio station found at 103.1 on the FM dial broadcasts at a frequency of 1.031 × 10 8 s −1 (103.1 MHz). What is the wavelength of these radio waves in meters?

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FM-95, an FM radio station, broadcasts at a frequency of 9.51 × 10 7 s −1 (95.1 MHz). What is the wavelength of these radio waves in meters?

3.15 m

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A bright violet line occurs at 435.8 nm in the emission spectrum of mercury vapor. What amount of energy, in joules, must be released by an electron in a mercury atom to produce a photon of this light?

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Light with a wavelength of 614.5 nm looks orange. What is the energy, in joules, per photon of this orange light? What is the energy in eV (1 eV = 1.602 × 10 −19 J)?

3.233 × 10 −19 J; 2.018 eV

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Heated lithium atoms emit photons of light with an energy of 2.961 × 10 −19 J. Calculate the frequency and wavelength of one of these photons. What is the total energy in 1 mole of these photons? What is the color of the emitted light?

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A photon of light produced by a surgical laser has an energy of 3.027 × 10 −19 J. Calculate the frequency and wavelength of the photon. What is the total energy in 1 mole of photons? What is the color of the emitted light?

ν = 4.568 × 10 14 s; λ = 656.3 nm; Energy mol −1 = 1.823 × 10 5 J mol −1 ; red

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When rubidium ions are heated to a high temperature, two lines are observed in its line spectrum at wavelengths (a) 7.9 × 10 −7 m and (b) 4.2 × 10 −7 m. What are the frequencies of the two lines? What color do we see when we heat a rubidium compound?

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The emission spectrum of cesium contains two lines whose frequencies are (a) 3.45 × 10 14 Hz and (b) 6.53 × 10 14 Hz. What are the wavelengths and energies per photon of the two lines? What color are the lines?

(a) λ = 8.69 × 10 −7 m; E = 2.29 × 10 −19 J; (b) λ = 4.59 × 10 −7 m; E = 4.33 × 10 −19 J; The color of (a) is red; (b) is blue.

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Photons of infrared radiation are responsible for much of the warmth we feel when holding our hands before a fire. These photons will also warm other objects. How many infrared photons with a wavelength of 1.5 × 10 −6 m must be absorbed by the water to warm a cup of water (175 g) from 25.0 °C to 40 °C?

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One of the radiographic devices used in a dentist's office emits an X-ray of wavelength 2.090 × 10 −11 m. What is the energy, in joules, and frequency of this X-ray?

E = 9.502 × 10 −15 J; ν = 1.434 × 10 19 s −1

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The eyes of certain reptiles pass a single visual signal to the brain when the visual receptors are struck by photons of a wavelength of 850 nm. If a total energy of 3.15 × 10 −14 J is required to trip the signal, what is the minimum number of photons that must strike the receptor?

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RGB color television and computer displays use cathode ray tubes that produce colors by mixing red, green, and blue light. If we look at the screen with a magnifying glass, we can see individual dots turn on and off as the colors change. Using a spectrum of visible light, determine the approximate wavelength of each of these colors. What is the frequency and energy of a photon of each of these colors?

Red: 660 nm; 4.54 × 10 14 Hz; 3.01 × 10 −19 J. Green: 520 nm; 5.77 × 10 14 Hz; 3.82 × 10 −19 J. Blue: 440 nm; 6.81 × 10 14 Hz; 4.51 × 10 −19 J. Somewhat different numbers are also possible.

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Answer the following questions about a Blu-ray laser:

(a) The laser on a Blu-ray player has a wavelength of 405 nm. In what region of the electromagnetic spectrum is this radiation? What is its frequency?

(b) A Blu-ray laser has a power of 5 milliwatts (1 watt = 1 J s −1 ). How many photons of light are produced by the laser in 1 hour?

(c) The ideal resolution of a player using a laser (such as a Blu-ray player), which determines how close together data can be stored on a compact disk, is determined using the following formula: Resolution = 0.60( λ /NA), where λ is the wavelength of the laser and NA is the numerical aperture. Numerical aperture is a measure of the size of the spot of light on the disk; the larger the NA, the smaller the spot. In a typical Blu-ray system, NA = 0.95. If the 405-nm laser is used in a Blu-ray player, what is the closest that information can be stored on a Blu-ray disk?

(d) The data density of a Blu-ray disk using a 405-nm laser is 1.5 × 10 7 bits mm −2 . Disks have an outside diameter of 120 mm and a hole of 15-mm diameter. How many data bits can be contained on the disk? If a Blu-ray disk can hold 9,400,000 pages of text, how many data bits are needed for a typed page? (Hint: Determine the area of the disk that is available to hold data. The area inside a circle is given by A = πr 2 , where the radius r is one-half of the diameter.)

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What is the threshold frequency for sodium metal if a photon with frequency 6.66 × 10 14 s −1 ejects an electron with 7.74 × 10 −20 J kinetic energy? Will the photoelectric effect be observed if sodium is exposed to orange light?

5.49 × 10 14 s −1 ; no

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Questions & Answers

differentiate between demand and supply giving examples
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In economics, a perfect market refers to a theoretical construct where all participants have perfect information, goods are homogenous, there are no barriers to entry or exit, and prices are determined solely by supply and demand. It's an idealized model used for analysis,
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When MP₁ becomes negative, TP start to decline. Extuples Suppose that the short-run production function of certain cut-flower firm is given by: Q=4KL-0.6K2 - 0.112 • Where is quantity of cut flower produced, I is labour input and K is fixed capital input (K-5). Determine the average product of lab
Kelo
Extuples Suppose that the short-run production function of certain cut-flower firm is given by: Q=4KL-0.6K2 - 0.112 • Where is quantity of cut flower produced, I is labour input and K is fixed capital input (K-5). Determine the average product of labour (APL) and marginal product of labour (MPL)
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What is different between quantity demand and demand?
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Quantity demanded refers to the specific amount of a good or service that consumers are willing and able to purchase at a give price and within a specific time period. Demand, on the other hand, is a broader concept that encompasses the entire relationship between price and quantity demanded
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Economic growth as an increase in the production and consumption of goods and services within an economy.but Economic development as a broader concept that encompasses not only economic growth but also social & human well being.
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In economics, the contract curve refers to the set of points in an Edgeworth box diagram where both parties involved in a trade cannot be made better off without making one of them worse off. It represents the Pareto efficient allocations of goods between two individuals or entities, where neither p
Cornelius
In economics, the contract curve refers to the set of points in an Edgeworth box diagram where both parties involved in a trade cannot be made better off without making one of them worse off. It represents the Pareto efficient allocations of goods between two individuals or entities,
Cornelius
Suppose a consumer consuming two commodities X and Y has The following utility function u=X0.4 Y0.6. If the price of the X and Y are 2 and 3 respectively and income Constraint is birr 50. A,Calculate quantities of x and y which maximize utility. B,Calculate value of Lagrange multiplier. C,Calculate quantities of X and Y consumed with a given price. D,alculate optimum level of output .
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Answer
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the market for lemon has 10 potential consumers, each having an individual demand curve p=101-10Qi, where p is price in dollar's per cup and Qi is the number of cups demanded per week by the i th consumer.Find the market demand curve using algebra. Draw an individual demand curve and the market dema
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suppose the production function is given by ( L, K)=L¼K¾.assuming capital is fixed find APL and MPL. consider the following short run production function:Q=6L²-0.4L³ a) find the value of L that maximizes output b)find the value of L that maximizes marginal product
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types of unemployment
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What is the difference between perfect competition and monopolistic competition?
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Source:  OpenStax, Chemistry. OpenStax CNX. May 20, 2015 Download for free at http://legacy.cnx.org/content/col11760/1.9
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