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Although the Group 12 metals ( [link] ) are formally part of the d-block elements from their position in the Periodic Table, their electronic configuration in both their elemental form ( d 10 s 2 ) and the vast majority of their compounds ( d 10 ) is that of the main group elements. The common oxidation state for all the Group 12 elements is +2, and the chemistry of zinc and cadmium compounds in particular is very similar to the analogous magnesium derivatives.

The IUPAC (International Union of Pure and Applied Chemistry) definition of a transition metal (or transition element) states that a transition metal is "an element whose atom has an incomplete d sub-shell, or which can give rise to cations with an incomplete d sub-shell." Thus, Group 12 elements are not transition metals.
Derivation of the names of the Group 12 metals.
Element Symbol Name
Zinc Zn From German zinke , meaning tooth-like, pointed or jagged (metallic zinc crystals have a needle-like appearance), or meaning tin-like because of its relation to German word zinn meaning tin , or from Persian seng meaning stone .
Cadmium Cd From the Latin cadmia , meaning calamine
Mercury Hg From the Latin hydrargyrum , meaning watery or liquid silver

Discovery

Zinc

Artifacts with a high zinc content (as much as 90%) have been fond to be over 2500 years old, and possibly older. As such it is clear that several cultures had the knowledge of working with zinc alloys, in particular brass (a zinc/copper alloy). Zinc mines at Zawar, near Udaipur in India, have been active since the late 1 st millennium BC. However, the smelting of metallic zinc appears to have begun around the 12 th century AD.

The isolation of purified metallic zinc was reported concurrently by several people. The extraction of zinc from its oxide (ZnO) was reported as early as 1668, while John Lane is supposed to have smelted zinc in 1726. The first Patent for zinc smelting was granted to English metallurgist William Champion in 1738; however, the credit for discovering pure metallic zinc is often given to Andreas Marggraf ( [link] ) in 1746.

Engraving of German chemist Andreas Sigismund Marggraf (1709 –1782).

Cadmium

Cadmium was discovered in 1817 by Friedrich Stromeyer ( [link] ) as an impurity in calamine (zinc carbonate, ZnCO 3 ). Stromeyer observed that impure samples of calamine changed color when heated but pure calamine did not. Eventually he was able to isolate cadmium metal by roasting and reduction of the sulfide.

German chemist Friedrich Stromeyer (1776 - 1835).

Mercury

Mercury was known to the ancient Chinese and was found in Egyptian tombs that date from 1500 BC. In China and Tibet, mercury use was thought to prolong life, heal fractures, and maintain generally good health. The ancient Greeks used mercury in ointments; the ancient Egyptians and the Romans used it in cosmetics that sometimes deformed the face.

Abundance

The Group 12 elements mainly occur in sulfide ores, however, as with their Group 2 analogs, carbonate are known, but not as economically viable. The major zinc containing ore is zinc blende (also known as sphalerite), which is zinc sulfide (ZnS). Other important ores include, wurtzite (ZnS), smithsonite (zinc carbonate, ZnCO 3 ), and hemimorphite (calamine, Zn 2 SiO 4 ). The basic form of zinc carbonate (hydrozincite, Zn 5 (CO 3 ) 2 (OH) 6 ) is also mined where economically viable. The main source of cadmium is as an impurity in zinc blende; however, there are several other ores known, e.g., cadmoselite (cadmium selenide, CdSe) and otavite (CdCO 3 ). Mercury sulfide (cinnabar, HgS) is the major source of mercury, and in fact metallic liquid mercury droplets are often found in the ore. The terrestrial abundance of the Group 12 elements is given in [link] .

Questions & Answers

can someone help me with some logarithmic and exponential equations.
Jeffrey Reply
sure. what is your question?
ninjadapaul
20/(×-6^2)
Salomon
okay, so you have 6 raised to the power of 2. what is that part of your answer
ninjadapaul
I don't understand what the A with approx sign and the boxed x mean
ninjadapaul
it think it's written 20/(X-6)^2 so it's 20 divided by X-6 squared
Salomon
I'm not sure why it wrote it the other way
Salomon
I got X =-6
Salomon
ok. so take the square root of both sides, now you have plus or minus the square root of 20= x-6
ninjadapaul
oops. ignore that.
ninjadapaul
so you not have an equal sign anywhere in the original equation?
ninjadapaul
Commplementary angles
Idrissa Reply
hello
Sherica
im all ears I need to learn
Sherica
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Tamia
what is a good calculator for all algebra; would a Casio fx 260 work with all algebra equations? please name the cheapest, thanks.
Kevin Reply
a perfect square v²+2v+_
Dearan Reply
kkk nice
Abdirahman Reply
algebra 2 Inequalities:If equation 2 = 0 it is an open set?
Kim Reply
or infinite solutions?
Kim
The answer is neither. The function, 2 = 0 cannot exist. Hence, the function is undefined.
Al
y=10×
Embra Reply
if |A| not equal to 0 and order of A is n prove that adj (adj A = |A|
Nancy Reply
rolling four fair dice and getting an even number an all four dice
ramon Reply
Kristine 2*2*2=8
Bridget Reply
Differences Between Laspeyres and Paasche Indices
Emedobi Reply
No. 7x -4y is simplified from 4x + (3y + 3x) -7y
Mary Reply
is it 3×y ?
Joan Reply
J, combine like terms 7x-4y
Bridget Reply
im not good at math so would this help me
Rachael Reply
yes
Asali
I'm not good at math so would you help me
Samantha
what is the problem that i will help you to self with?
Asali
how do you translate this in Algebraic Expressions
linda Reply
Need to simplify the expresin. 3/7 (x+y)-1/7 (x-1)=
Crystal Reply
. After 3 months on a diet, Lisa had lost 12% of her original weight. She lost 21 pounds. What was Lisa's original weight?
Chris Reply
what's the easiest and fastest way to the synthesize AgNP?
Damian Reply
China
Cied
types of nano material
abeetha Reply
I start with an easy one. carbon nanotubes woven into a long filament like a string
Porter
many many of nanotubes
Porter
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Yasmin
what is the function of carbon nanotubes?
Cesar
what is nanomaterials​ and their applications of sensors.
Ramkumar Reply
what is nano technology
Sravani Reply
what is system testing?
AMJAD
preparation of nanomaterial
Victor Reply
Yes, Nanotechnology has a very fast field of applications and their is always something new to do with it...
Himanshu Reply
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AMJAD
what is system testing
AMJAD
what is the application of nanotechnology?
Stotaw
In this morden time nanotechnology used in many field . 1-Electronics-manufacturad IC ,RAM,MRAM,solar panel etc 2-Helth and Medical-Nanomedicine,Drug Dilivery for cancer treatment etc 3- Atomobile -MEMS, Coating on car etc. and may other field for details you can check at Google
Azam
anybody can imagine what will be happen after 100 years from now in nano tech world
Prasenjit
after 100 year this will be not nanotechnology maybe this technology name will be change . maybe aftet 100 year . we work on electron lable practically about its properties and behaviour by the different instruments
Azam
name doesn't matter , whatever it will be change... I'm taking about effect on circumstances of the microscopic world
Prasenjit
how hard could it be to apply nanotechnology against viral infections such HIV or Ebola?
Damian
silver nanoparticles could handle the job?
Damian
not now but maybe in future only AgNP maybe any other nanomaterials
Azam
can nanotechnology change the direction of the face of the world
Prasenjit Reply
At high concentrations (>0.01 M), the relation between absorptivity coefficient and absorbance is no longer linear. This is due to the electrostatic interactions between the quantum dots in close proximity. If the concentration of the solution is high, another effect that is seen is the scattering of light from the large number of quantum dots. This assumption only works at low concentrations of the analyte. Presence of stray light.
Ali Reply
the Beer law works very well for dilute solutions but fails for very high concentrations. why?
bamidele Reply
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Source:  OpenStax, Chemistry of the main group elements. OpenStax CNX. Aug 20, 2010 Download for free at http://cnx.org/content/col11124/1.25
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