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Since the part of the light that is not reflected is refracted, the amount of polarization depends on the indices of refraction of the media involved. It can be shown that reflected light is completely polarized at an angle of reflection θ b given by

tan θ b = n 2 n 1

where n 1 is the medium in which the incident and reflected light travel and n 2 is the index of refraction of the medium that forms the interface that reflects the light. This equation is known as Brewster’s law    and θ b is known as Brewster’s angle    , named after the nineteenth-century Scottish physicist who discovered them.

This Open Source Physics animation shows incident, reflected, and refracted light as rays and EM waves. Try rotating the animation for 3D visualization and also change the angle of incidence. Near Brewster’s angle, the reflected light becomes highly polarized.

Calculating polarization by reflection

(a) At what angle will light traveling in air be completely polarized horizontally when reflected from water? (b) From glass?

Strategy

All we need to solve these problems are the indices of refraction. Air has n 1 = 1.00 , water has n 2 = 1.333 , and crown glass has n 2 = 1.520 . The equation tan θ b = n 2 n 1 can be directly applied to find θ b in each case.

Solution

  1. Putting the known quantities into the equation
    tan θ b = n 2 n 1

    gives
    tan θ b = n 2 n 1 = 1.333 1.00 = 1.333 .

    Solving for the angle θ b yields
    θ b = tan −1 1.333 = 53.1 ° .
  2. Similarly, for crown glass and air,
    tan θ b = n 2 n 1 = 1.520 1.00 = 1.52 .

    Thus,
    θ b = tan −1 1.52 = 56.7 ° .

Significance

Light reflected at these angles could be completely blocked by a good polarizing filter held with its axis vertical. Brewster’s angle for water and air are similar to those for glass and air, so that sunglasses are equally effective for light reflected from either water or glass under similar circumstances. Light that is not reflected is refracted into these media. Therefore, at an incident angle equal to Brewster’s angle, the refracted light is slightly polarized vertically. It is not completely polarized vertically, because only a small fraction of the incident light is reflected, so a significant amount of horizontally polarized light is refracted.

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Check Your Understanding What happens at Brewster’s angle if the original incident light is already 100 % vertically polarized?

There will be only refraction but no reflection.

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Atomic explanation of polarizing filters

Polarizing filters have a polarization axis that acts as a slit. This slit passes EM waves (often visible light) that have an electric field parallel to the axis. This is accomplished with long molecules aligned perpendicular to the axis, as shown in [link] .

The figure shows an illustration of a  stack of long identical horizontal molecules. A vertical axis is drawn over the molecules.
Long molecules are aligned perpendicular to the axis of a polarizing filter. In an EM wave, the component of the electric field perpendicular to these molecules passes through the filter, whereas the component parallel to the molecules is absorbed.

[link] illustrates how the component of the electric field parallel to the long molecules is absorbed. An EM wave is composed of oscillating electric and magnetic fields. The electric field is strong compared with the magnetic field and is more effective in exerting force on charges in the molecules. The most affected charged particles are the electrons, since electron masses are small. If an electron is forced to oscillate, it can absorb energy from the EM wave. This reduces the field in the wave and, hence, reduces its intensity. In long molecules, electrons can more easily oscillate parallel to the molecule than in the perpendicular direction. The electrons are bound to the molecule and are more restricted in their movement perpendicular to the molecule. Thus, the electrons can absorb EM waves that have a component of their electric field parallel to the molecule. The electrons are much less responsive to electric fields perpendicular to the molecule and allow these fields to pass. Thus, the axis of the polarizing filter is perpendicular to the length of the molecule.

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Source:  OpenStax, University physics volume 3. OpenStax CNX. Nov 04, 2016 Download for free at http://cnx.org/content/col12067/1.4
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