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By the end of this section, you will be able to:
  • Explain how a mass spectrometer works to separate charges
  • Explain how a cyclotron works

Being able to manipulate and sort charged particles allows deeper experimentation to understand what matter is made of. We first look at a mass spectrometer to see how we can separate ions by their charge-to-mass ratio. Then we discuss cyclotrons as a method to accelerate charges to very high energies.

Mass spectrometer

The mass spectrometer    is a device that separates ions according to their charge-to-mass ratios. One particular version, the Bainbridge mass spectrometer, is illustrated in [link] . Ions produced at a source are first sent through a velocity selector, where the magnetic force is equally balanced with the electric force. These ions all emerge with the same speed v = E / B since any ion with a different velocity is deflected preferentially by either the electric or magnetic force, and ultimately blocked from the next stage. They then enter a uniform magnetic field B 0 where they travel in a circular path whose radius R is given by [link] . The radius is measured by a particle detector located as shown in the figure.

A schematic of the Bainbridge mass spectrometer. Charged particles moving down enter a region with electric field E pointing to the left and magnetic field B pointing into the page. The particle path continues in a straight line until it enters a region with no electric field. The magnetic field here is uniform, into the page, and magnitude B naught. The particle path in this region curves in a counterclockwise circle of radius R until it hits a particle detector.
A schematic of the Bainbridge mass spectrometer, showing charged particles leaving a source, followed by a velocity selector where the electric and magnetic forces are balanced, followed by a region of uniform magnetic field where the particle is ultimately detected.

The relationship between the charge-to-mass ratio q / m and the radius R is determined by combining [link] and [link] :

q m = E B B 0 R .

Since most ions are singly charged ( q = 1.6 × 10 −19 C ) , measured values of R can be used with this equation to determine the mass of ions. With modern instruments, masses can be determined to one part in 10 8 .

An interesting use of a spectrometer is as part of a system for detecting very small leaks in a research apparatus. In low-temperature physics laboratories, a device known as a dilution refrigerator uses a mixture of He-3, He-4, and other cryogens to reach temperatures well below 1 K. The performance of the refrigerator is severely hampered if even a minute leak between its various components occurs. Consequently, before it is cooled down to the desired temperature, the refrigerator is subjected to a leak test. A small quantity of gaseous helium is injected into one of its compartments, while an adjacent, but supposedly isolated, compartment is connected to a high-vacuum pump to which a mass spectrometer is attached. A heated filament ionizes any helium atoms evacuated by the pump. The detection of these ions by the spectrometer then indicates a leak between the two compartments of the dilution refrigerator.

In conjunction with gas chromatography, mass spectrometers are used widely to identify unknown substances. While the gas chromatography portion breaks down the substance, the mass spectrometer separates the resulting ionized molecules. This technique is used with fire debris to ascertain the cause, in law enforcement to identify illegal drugs, in security to identify explosives, and in many medicinal applications.

Questions & Answers

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Communication is effective because it allows individuals to share ideas, thoughts, and information with others.
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Source:  OpenStax, University physics volume 2. OpenStax CNX. Oct 06, 2016 Download for free at http://cnx.org/content/col12074/1.3
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