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Chemical equilibrium

Having looked at factors that affect the rate of a reaction, we now need to ask some important questions. Does a reaction always proceed in the same direction or can it be reversible? In other words, is it always true that a reaction proceeds from reactants to products , or is it possible that sometimes, the reaction will reverse and the products will be changed back into the reactants ? And does a reaction always run its full course so that all the reactants are used up, or can a reaction reach a point where reactants are still present, but there does not seem to be any further change taking place in the reaction? The following demonstration might help to explain this.

Demonstration : liquid-vapour phase equilibrium

Apparatus and materials:

2 beakers; water; bell jar


  1. Half fill two beakers with water and mark the level of the water in each case.
  2. Cover one of the beakers with a bell jar.
  3. Leave the beakers and, over the course of a day or two, observe how the water level in the two beakers changes. What do you notice? Note: You could speed up this demonstration by placing the two beakers over a bunsen burner to heat the water. In this case, it may be easier to cover the second beaker with a glass cover.


You should notice that in the beaker that is uncovered, the water level drops quickly because of evaporation. In the beaker that is covered, there is an initial drop in the water level, but after a while evaporation appears to stop and the water level in this beaker is higher than that in the one that is open. Note that the diagram below shows the situation ate time=0.


In the first beaker, liquid water becomes water vapour as a result of evaporation and the water level drops. In the second beaker, evaporation also takes place. However, in this case, the vapour comes into contact with the surface of the bell jar and it cools and condenses to form liquid water again. This water is returned to the beaker. Once condensation has begun, the rate at which water is lost from the beaker will start to decrease. At some point, the rate of evaporation will be equal to the rate of condensation above the beaker, and there will be no change in the water level in the beaker. This can be represented as follows:

l i q u i d v a p o u r

In this example, the reaction (in this case, a change in the phase of water) can proceed in either direction. In one direction there is a change in phase from liquid to vapour. But the reverse can also take place, when vapour condenses to form water again.

In a closed system it is possible for reactions to be reversible, such as in the demonstration above. In a closed system, it is also possible for a chemical reaction to reach equilibrium . We will discuss these concepts in more detail.

Open and closed systems

An open system is one in which matter or energy can flow into or out of the system. In the liquid-vapour demonstration we used, the first beaker was an example of an open system because the beaker could be heated or cooled (a change in energy ), and water vapour (the matter ) could evaporate from the beaker.

Questions & Answers

what does the word emitted mean?
Mwinga Reply
to be ejected or released
Ok thanks
what are the hooke laws
Tyriek Reply
what do really asked in exam
Leiyo Reply
hi please help me how to balance redox reactions?
Brian Reply
Which equation do u wanna balance
i tried to write it but my phone just can't write it Cr2 O72-(aq) + H2S (aq) Cr3 (aq) + S(s)
show is the equation
hello. what is the difference between a primary, secondary and tertiary alcohol
Thokozani Reply
primary the C=bonded to 1 Carbon atom.... secondary=bonded to 2 carbon atoms tertiary=bonded to 3 carbon atoms
I hope you're answered
thanks Christina
My pleasure
Thank you Christina. This is very helpful 😀👍👍💯
Anytime Thokozani
How to calculate pH?
thank you guys i didn't know about the primary, secondary and tertiary alcohols
thank you Christina
Hey guys which topic does AC nd DC generator falls
thank you
can somebody help me with functional isomers
Baningi Reply
function isomer has the same molecular formula but different functional group
what's momentum
Luvelo Reply
the product of an objects mass times velocity. it is mainly prevalent in collisions.
in order to produce an interference pattern, the waves used must be what?
Methane contains C and H. This compound is
Juan Reply
ketones's functional group
Moloi Reply
Why does the carboxyl group have acidc properties?
Evi Reply
carboxylic acids
Besides improving appearance what is another reason why medal is electro plated
Elizabeth Reply
it is made of metal
what is different between Dependent variable and independent variables
difference between A.c and D.c
AC has slip rings DC has split rings commutator
to avoid rust and to improve strength and conductivity
the variable whose value doesn't depend on other is known as independent variable ex time
are UV rays dangerous?
Khathutshelo Reply
what's this?
if there is extensive exposure, it can lead to skin cancer
yes depend upon their intensity
i hv a problem with this chapter because i also have problem with Newton's laws of motion
Kearabetswe Reply
I have a problem with calculation in Newton's law of motion
me also VuyokAzi
what's the question
Which area in particular?
just get the hang if free body diagrams,know the directions.
I know how to draw free diagram I have a problem with calculation in second law
what is the wave model of atom ?
Trazy Reply
guys what is momentum
@Luvelo... Momentum is the product of an object's mass and its velocity.
the model based on wave nature of electron
Can you state the Doppler effect in words
Nombuyiselo Reply
State Coulomb's law in words
the magnitude of the electrostatic force exerted point on each other is directly proportional to the product on magnitude of charges and inversely proportional to the square distance between them
the change in frequency of the sound detected by a listener because sound source and listener have different velocity

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Source:  OpenStax, Siyavula textbooks: grade 12 physical science. OpenStax CNX. Aug 03, 2011 Download for free at http://cnx.org/content/col11244/1.2
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