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The distribution of particle kinetic energies at a fixed temperature

A catalyst functions slightly differently. The function of a catalyst is to lower the activation energy so that more particles now have enough energy to react. The catalyst itself is not changed during the reaction, but simply provides an alternative pathway for the reaction, so that it needs less energy. Some metals e.g. platinum, copper and iron can act as catalysts in certain reactions. In our own human bodies, enzymes are catalysts that help to speed up biological reactions. Catalysts generally react with one or more of the reactants to form a chemical intermediate which then reacts to form the final product. The chemical intermediate is sometimes called the activated complex .

The following is an example of how a reaction that involves a catalyst might proceed. C represents the catalyst, A and B are reactants and D is the product of the reaction of A and B.

Step 1: A + C AC

Step 2: B + AC ABC

Step 3: ABC CD

Step 4: CD C + D

In the above, ABC represents the intermediate chemical. Although the catalyst (C) is consumed by reaction 1, it is later produced again by reaction 4, so that the overall reaction is as follows:

A + B + C D + C

You can see from this that the catalyst is released at the end of the reaction, completely unchanged.

Catalyst

A catalyst speeds up a chemical reaction, without being altered in any way. It increases the reaction rate by lowering the activation energy for a reaction.

Energy diagrams are useful to illustrate the effect of a catalyst on reaction rates. Catalysts decrease the activation energy required for a reaction to proceed (shown by the smaller 'hump' on the energy diagram in [link] ), and therefore increase the reaction rate.

The effect of a catalyst on the activation energy of a reaction

Experiment : catalysts and reaction rates

Aim:

To determine the effect of a catalyst on the rate of a reaction

Apparatus:

Zinc granules, 0.1 M hydrochloric acid, copper pieces, one test tube and a glass beaker.

Method:

  1. Place a few of the zinc granules in the test tube.
  2. Measure the mass of a few pieces of copper and keep them separate from the rest of the copper.
  3. Add about 20 cm 3 of HCl to the test tube. You will see that a gas is released. Take note of how quickly or slowly this gas is released. Write a balanced equation for the chemical reaction that takes place.
  4. Now add the copper pieces to the same test tube. What happens to the rate at which the gas is produced?
  5. Carefully remove the copper pieces from the test tube (do not get HCl on your hands), rinse them in water and alcohol and then weigh them again. Has the mass of the copper changed since the start of the experiment?

Results:

During the reaction, the gas that is released is hydrogen. The rate at which the hydrogen is produced increases when the copper pieces (the catalyst) are added. The mass of the copper does not change during the reaction.

Conclusions:

The copper acts as a catalyst during the reaction. It speeds up the rate of the reaction, but is not changed in any way itself.

Reaction rates

  1. For each of the following, say whether the statement is true or false . If it is false, re-write the statement correctly.
    1. A catalyst increases the energy of reactant molecules so that a chemical reaction can take place.
    2. Increasing the temperature of a reaction has the effect of increasing the number of reactant particles that have more energy that the activation energy.
    3. A catalyst does not become part of the final product in a chemical reaction.
  2. 5 g of zinc granules are added to 400 cm 3 of 0.5 mol.dm - 3 hydrochloric acid. To investigate the rate of the reaction, the change in the mass of the flask containing the zinc and the acid was measured by placing the flask on a direct reading balance. The reading on the balance shows that there is a decrease in mass during the reaction. The reaction which takes place is given by the following equation: Z n ( s ) + 2 H C l ( a q ) Z n C l 2 ( a q ) + H 2 ( g )
    1. Why is there a decrease in mass during the reaction?
    2. The experiment is repeated, this time using 5 g of powdered zinc instead of granulated zinc. How will this influence the rate of the reaction?
    3. The experiment is repeated once more, this time using 5 g of granulated zinc and 600 cm 3 of 0.5 mol.dm - 3 hydrochloric acid. How does the rate of this reaction compare to the original reaction rate?
    4. What effect would a catalyst have on the rate of this reaction?
    (IEB Paper 2 2003)
  3. Enzymes are catalysts. Conduct your own research to find the names of common enzymes in the human body and which chemical reactions they play a role in.
  4. 5 g of calcium carbonate powder reacts with 20 cm 3 of a 0.1 mol.dm - 3 solution of hydrochloric acid. The gas that is produced at a temperature of 25 c i r c C is collected in a gas syringe.
    1. Write a balanced chemical equation for this reaction.
    2. The rate of the reaction is determined by measuring the volume of gas thas is produced in the first minute of the reaction. How would the rate of the reaction be affected if:
      1. a lump of calcium carbonate of the same mass is used
      2. 40 cm 3 of 0.1 mol.dm - 3 hydrochloric acid is used

Questions & Answers

which quantity is measured in Watt?
Saara Reply
work
Absai
explain for me absai
Sboniso
what is galvanic cell ?
Oratile Reply
is an electrochemical cell that derives electrical energy from spontaneous redox reactions taking place within the cell.
Hope
how to understand alkane names
Sboniso Reply
suffix Ane in the IUPAC NAMING
Madman
What are hydrocarbons
Phelo Reply
are organic Compounds with only Carbon and Hydrogen Atoms
Madman
whats the difference between aldehydes and ketones
Angel Reply
definition of chain parent
Lea Reply
what is wave?
Agness Reply
when butane burns in an excess of oxygen ,the products are
Slay
CO2 and H2O
GARY
Carbon dioxide and Water...
Thato
what is hydrocarbon
Ntswaki Reply
Hydrocarbon is a compostion of mainy carbon and hydrogen
Tsion
hydrocarbon compound made up of carbon and hydrogen only
Thembelani
25 element of physics
musah Reply
an object will remain at rest or move at a constant velocity unless acted upon a net force
Lebogang Reply
thank you
Thabiso
law of inertia
Joan
an object resisting the change in velocity.
Thabiso
newton first law of motion
Tshepo
An object will remain at rest, unless an unbalanced force acts on it.
Anga
or uniform motion
Thato
What is a molecule
Thabiso Reply
a molecule is a simplest structure unite of an elements
Else
thank you
Thabiso
Plz remind me the 1st Newton's law
Thabiso
Define the term functinal group of an organic compound
Kamvelihle Reply
a single atom or a group of atoms which is responsible for the property and function of an organic compound
Shandre
thanks😊
Kamvelihle
What's the relationship between intensity and the current?
Lufuno Reply
yu are Spi.ke spanish hola ele
Rolamf
cómo se llama el video donde disquete salgo yo
Rolamf
The intensity doesn't effect the current.
Mosa
what does the word emitted mean?
Mwinga Reply
to be ejected or released
Khathutshelo
Ok thanks
Mwinga
Released
Mosa
what are the hooke laws
Tyriek Reply
what's that
Mosa

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Source:  OpenStax, Siyavula textbooks: grade 12 physical science. OpenStax CNX. Aug 03, 2011 Download for free at http://cnx.org/content/col11244/1.2
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