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A comparison of exothermic and endothermic reactions
Type of reaction Exothermic Endothermic
Energy absorbed or released Released Absorbed
Relative energy of reactants and products Energy of reactants greater than energy of product Energy of reactants less than energy of product
Sign of Δ H Negative Positive
Writing equations using Δ H

There are two ways to write the heat of the reaction in an equation

For the exothermic reaction C ( s ) + O 2 ( g ) C O 2 ( g ) , we can write:

C ( s ) + O 2 ( g ) C O 2 ( g ) Δ H = -393 kJ.mol - 1 or

C ( s ) + O 2 ( g ) C O 2 ( g ) + 393 kJ.mol - 1

For the endothermic reaction, C ( s ) + H 2 O ( g ) H 2 ( g ) + C O ( g ) , we can write:

C ( s ) + H 2 O ( g ) H 2 ( g ) + C O ( g ) Δ H = +131 kJ.mol - 1 or

C ( s ) + H 2 O ( g ) + 131 kJ.mol - 1 C O + H 2

The units for Δ H are kJ.mol - 1 . In other words, the Δ H value gives the amount of energy that is absorbed or released per mole of product that is formed. Units can also be written as kJ, which then gives the total amount of energy that is released or absorbed when the product forms.

Investigation : endothermic and exothermic reactions

Apparatus and materials:

Approximately 2 g each of calcium chloride (CaCl 2 ), sodium hydroxide (NaOH), potassium nitrate (KNO 3 ) and barium chloride (BaCl 2 ); concentrated sulfuric acid (H 2 SO 4 ) (Be Careful, this can cause serious burns) ; 5 test tubes; thermometer.

Method:

  1. Dissolve about 1 g of each of the following substances in 5-10 cm 3 of water in a test tube: CaCl 2 , NaOH, KNO 3 and BaCl 2 .
  2. Observe whether the reaction is endothermic or exothermic, either by feeling whether the side of the test tube gets hot or cold, or using a thermometer.
  3. Dilute 3 cm 3 of concentrated H 2 SO 4 in 10 cm 3 of water in the fifth test tube and observe whether the temperature changes.
  4. Wait a few minutes and then carefully add NaOH to the H 2 SO 4 . Observe any energy changes.
  5. Record which of the above reactions are endothermic and which are exothermic.

Results:

  • When BaCl 2 and KNO 3 dissolve in water, they take in heat from the surroundings. The dissolution of these salts is endothermic .
  • When CaCl 2 and NaOH dissolve in water, heat is released. The process is exothermic .
  • The reaction of H 2 SO 4 and NaOH is also exothermic .

Examples of endothermic and exothermic reactions

There are many examples of endothermic and exothermic reactions that occur around us all the time. The following are just a few examples.

  1. Endothermic reactions
    • Photosynthesis Photosynthesis is the chemical reaction that takes place in plants, which uses energy from the sun to change carbon dioxide and water into food that the plant needs to survive, and which other organisms (such as humans and other animals) can eat so that they too can survive. The equation for this reaction is: 6 CO 2 + 12 H 2 O + energy C 6 H 12 O 6 + 6 O 2 + 6 H 2 O Photosynthesis is an endothermic reaction because it will not happen without an external source of energy, which in this case is sunlight.
    • The thermal decomposition of limestone In industry, the breakdown of limestone into quicklime and carbon dioxide is very important. Quicklime can be used to make steel from iron and also to neutralise soils that are too acid. However, the limestone must be heated in a kiln at a temperature of over 900 0 C before the decomposition reaction will take place. The equation for the reaction is shown below: CaCO 3 CaO + CO 2
  2. Exothermic reactions
    • Combustion reactions - The burning of fuel is an example of a combustion reaction, and we as humans rely heavily on this process for our energy requirements. The following equations describe the combustion of a hydrocarbon such as methane (CH 4 ): Fuel + Oxygen Heat + Water + Carbon Dioxide CH 4 + 2 O 2 Heat + 2 H 2 O + CO 2 This is why we burn fuels for energy, because the chemical changes that take place during the reaction release huge amounts of energy, which we then use for things like power and electricity. You should also note that carbon dioxide is produced during this reaction. Later we will discuss some of the negative impacts of C O 2 on the environment. The chemical reaction that takes place when fuels burn therefore has both positive and negative consequences.
    • Respiration Respiration is the chemical reaction that happens in our bodies to produce energy for our cells. The equation below describes what happens during this reaction: C 6 H 12 O 6 + 6 O 2 6 CO 2 + 6 H 2 O + energy In the reaction above, glucose (a type of carbohydrate in the food we eat) reacts with oxygen from the air that we breathe in, to form carbon dioxide (which we breathe out), water and energy. The energy that is produced allows the cell to carry out its functions efficiently. Can you see now why you are always told that you must eat food to get energy? It is not the food itself that provides you with energy, but the exothermic reaction that takes place when compounds within the food react with the oxygen you have breathed in!

Questions & Answers

how to calculate the forces
Zenande Reply
how to calculate magnitude using Newton second law?
Karabo Reply
how to calculate a vector
Thabang Reply
how to calculate force
Mulalo Reply
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Kwanele Reply
how to calculate magnitude using Newton second law
Koketso Reply
what's the formula for calculating frictional force?
Ayanda Reply
how do we calculate the magnitude in Newton laws of motion
karabo Reply
What is dynamics
Phege Reply
When do we know that we are supposed to draw tail to head diagram?
Mary Reply
@Mary you can use the method that U understand better unless they specify which one to use and the head to tail method is helpful especially when you solve the vector problem graphically
busisiwe
for magnitude we/you can apply theorem of Pythagoras...in use of x-axis and y-axis then for direction we apply trig-ratios
Athandwe Reply
determine the frictional force acting on the box if a horizontal force is applied with a magnitude of a.0N b.20N c.40N and d.60N
Precious Reply
what is an Inertia
david Reply
how to identify if the is a net force acting on an object
Sthabiso Reply
two forces of 5N and 7N respectively act on an object, when will the resultant of two vectors be at a maximum?
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Source:  OpenStax, Siyavula textbooks: grade 11 physical science. OpenStax CNX. Jul 29, 2011 Download for free at http://cnx.org/content/col11241/1.2
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