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The p-n junction

Differences between p- and n-type semi-conductors

We have seen that the addition of specific elements to semiconductor materials turns them into p-type semiconductors or n-type semiconductors. The differences between n- and p-type semiconductors are summarised in [link] .

The p-n junction

When p-type and n-type semiconductors are placed in contact with each other, a p-n junction is formed. Near the junction, electrons and holes combine to create a depletion region.

The p-n junction forms between p- and n-type semiconductors. The free electrons from the n-type material combine with the holes in the p-type material near the junction. There is a small potential difference across the junction. The area near the junction is called the depletion region because there are few holes and few free electrons in this region.

Electric current flows more easily across a p-n junction in one direction than in the other. If the positive pole of a battery is connected to the p-side of the junction, and the negative pole to the n-side, charge flows across the junction. If the battery is connected in the opposite direction, very little charge can flow.

This might not sound very useful at first but the p-n junction forms the basis for computer chips, solar cells, and other electronic devices.

The following simulation allows you to see what happens in semi-conductors and to make semi-conductors.

run demo

Unbiased

In a p-n junction, without an external applied voltage (no bias), an equilibrium condition is reached in which a potential difference is formed across the junction.

P-type is where you have more "holes"; n-type is where you have more electrons in the material. Initially, when you put them together to form a junction, holes near the junction tends to "move" across to the n-region, while the electrons in the n-region drift across to the p-region to "fill" some holes. This current will quickly stop as the potential barrier is built up by the migrated charges. So in steady state no current flows.

Now when you put a potential different across the terminals you have two cases: forward biased and reverse biased.

Forward biased

Forward-bias occurs when the p-type semiconductor material is connected to the positive terminal of a battery and the n-type semiconductor material is connected to the negative terminal.

The electric field from the external potential different can easily overcome the small internal field (in the so-called depletion region, created by the initial drifting of charges): usually anything bigger than 0.6V would be enough. The external field then attracts more e- to flow from n-region to p-region and more holes from p-region to n-region and you have a forward biased situation. the diode is forward biased and so current will flow.

Reverse biased

In this case the external field pushes e- back to the n-region while more holes into the p-region, as a result you get no current flow. Only the small number of thermally released minority carriers (holes in the n-type region and e- in the p-type region) will be able to cross the junction and form a very small current, but for all practical purposes, this can be ignored.

Of course if the reverse biased potential is large enough you get what is called avalanche break down and current flow in the opposite direction. In many cases, except for Zener diodes, you most likely will destroy the diode.

Real-world applications of semiconductors

Semiconductors form the basis of modern electronics. Every electrical appliance usually has some semiconductor-based technology inside it. The fundamental uses of semiconductors are in microchips (also known as integrated circuits) and microprocessors.

Integrated circuits are miniaturised circuits. The use of integrated circuits makes it possible for electronic devices (like a cellular telephone or a hi-fi) to get smaller.

Microprocessors are a special type of integrated circuit.

Research project : semiconductors

Assess the impact on society of the invention of transistors, with particular reference to their use in microchips (integrated circuits) and microprocessors.

The p-n junction

  1. Compare p- and n-type semi-conductors.
  2. Explain how a p-n junction works using a diagram.
  3. Give everyday examples of the application.

End of chapter exercises

  1. What is a conductor?
  2. What is an insulator?
  3. What is a semiconductor?

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Source:  OpenStax, Siyavula textbooks: grade 11 physical science. OpenStax CNX. Jul 29, 2011 Download for free at http://cnx.org/content/col11241/1.2
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