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Making connections: take-home experiment—refrigerating a balloon

Inflate a balloon at room temperature. Leave the inflated balloon in the refrigerator overnight. What happens to the balloon, and why?

Calculating the number of molecules in a cubic meter of gas

How many molecules are in a typical object, such as gas in a tire or water in a drink? We can use the ideal gas law to give us an idea of how large N size 12{N} {} typically is.

Calculate the number of molecules in a cubic meter of gas at standard temperature and pressure (STP), which is defined to be 0 º C size 12{0°C} {} and atmospheric pressure.

Strategy

Because pressure, volume, and temperature are all specified, we can use the ideal gas law PV = NkT size 12{ ital "PV"= ital "NkT"} {} , to find N size 12{N} {} .

Solution

1. Identify the knowns.

T = 0 º C = 273 K P = 1 . 01 × 10 5 Pa V = 1 . 00 m 3 k = 1 . 38 × 10 23 J/K

2. Identify the unknown: number of molecules, N size 12{N} {} .

3. Rearrange the ideal gas law to solve for N size 12{N} {} .

PV = NkT N = PV kT alignl { stack { size 12{ ital "PV"= ital "NkT"} {} #size 12{N= { { ital "PV"} over { ital "kT"} } } {} } } {}

4. Substitute the known values into the equation and solve for N size 12{N} {} .

N = PV kT = 1 . 01 × 10 5 Pa 1 . 00 m 3 1 . 38 × 10 23 J/K 273 K = 2 . 68 × 10 25 molecules size 12{N= { { ital "PV"} over { ital "kT"} } = { { left (1 "." "01" times "10" rSup { size 8{5} } " Pa" right ) left (1 "." "00 m" rSup { size 8{3} } right )} over { left (1 "." "38" times "10" rSup { size 8{ - "23"} } " J/K" right ) left ("273 K" right )} } =2 "." "68" times "10" rSup { size 8{"25"} } `"molecules"} {}

Discussion

This number is undeniably large, considering that a gas is mostly empty space. N size 12{N} {} is huge, even in small volumes. For example, 1 cm 3 size 12{1" cm" rSup { size 8{3} } } {} of a gas at STP has 2 . 68 × 10 19 size 12{2 "." "68"´"10" rSup { size 8{"19"} } } {} molecules in it. Once again, note that N size 12{N} {} is the same for all types or mixtures of gases.

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Moles and avogadro’s number

It is sometimes convenient to work with a unit other than molecules when measuring the amount of substance. A mole    (abbreviated mol) is defined to be the amount of a substance that contains as many atoms or molecules as there are atoms in exactly 12 grams (0.012 kg) of carbon-12. The actual number of atoms or molecules in one mole is called Avogadro’s number     ( N A ) size 12{ \( N rSub { size 8{A} } \) } {} , in recognition of Italian scientist Amedeo Avogadro (1776–1856). He developed the concept of the mole, based on the hypothesis that equal volumes of gas, at the same pressure and temperature, contain equal numbers of molecules. That is, the number is independent of the type of gas. This hypothesis has been confirmed, and the value of Avogadro’s number is

N A = 6 . 02 × 10 23 mol 1 . size 12{N rSub { size 8{A} } =6 "." "02" times "10" rSup { size 8{"23"} } `"mol" rSup { size 8{ - 1} } "." } {}

Avogadro’s number

One mole always contains 6 . 02 × 10 23 size 12{6 "." "02"´"10" rSup { size 8{"23"} } } {} particles (atoms or molecules), independent of the element or substance. A mole of any substance has a mass in grams equal to its molecular mass, which can be calculated from the atomic masses given in the periodic table of elements.

N A = 6 . 02 × 10 23 mol 1 size 12{N rSub { size 8{A} } =6 "." "02" times "10" rSup { size 8{"23"} } `"mol" rSup { size 8{ - 1} } } {}
The illustration shows relatively flat land with a solitary mountain, labeled Mt. Everest, and blue sky above. A double-headed vertical arrow stretches between the land and a point in the sky that is well above the peak of the mountain. The arrow, labeled table tennis balls, serves to indicate that a column of one mole of table tennis balls would reach a point in the sky that is much higher than the peak of Mt. Everest.
How big is a mole? On a macroscopic level, one mole of table tennis balls would cover the Earth to a depth of about 40 km.

The active ingredient in a Tylenol pill is 325 mg of acetaminophen ( C 8 H 9 NO 2 ) size 12{ \( C rSub { size 8{8} } H rSub { size 8{9} } "NO" rSub { size 8{2} } \) } {} . Find the number of active molecules of acetaminophen in a single pill.

We first need to calculate the molar mass (the mass of one mole) of acetaminophen. To do this, we need to multiply the number of atoms of each element by the element’s atomic mass.

( 8 moles of carbon ) ( 12 grams/mole ) + ( 9 moles hydrogen ) ( 1 gram/mole ) + ( 1 mole nitrogen ) ( 14 grams/mole ) + ( 2 moles oxygen ) ( 16 grams/mole ) = 151 g

Then we need to calculate the number of moles in 325 mg.

325 mg 151 grams/mole 1 gram 1000 mg = 2.15 × 10 3 moles

Then use Avogadro’s number to calculate the number of molecules.

N = 2.15 × 10 3 moles 6.02 × 10 23 molecules/mole = 1.30 × 10 21 molecules size 12{N= left (2 "." "15" times "10" rSup { size 8{ - 3} } `"moles" right ) left (6 "." "02" times "10" rSup { size 8{"23"} } `"molecules/mole" right )=1 "." "30" times "10" rSup { size 8{"21"} } `"molecules"} {}
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Questions & Answers

what is normal force?
Neyaz Reply
the force that pushes upward on us. the force that opposes gravity
clifford
upthrust of air
Abdikadir
Newton's 3rd law. the force of the ground (earth) that pushes back on gravity, keeping us on the ground instead of sinking into it.
clifford
I really need lots of questions on frictional force
Ogboru Reply
Questions or answers?
Shii
I can help answering what I can
Shii
does friction also need some force to perform?
Mohit
no friction is a force just like the gravitational force
clifford
yeah but u can't apply friction anywhere else like other forces
Mohit
I don't understand that question. friction does work alongside other forces based on the situation.
clifford
eg. when walking there are two forces acting on us gravitational and frictional force. friction helps us move forward and gravity keeps us on the ground
clifford
friction is a contact force. Two surfaces are necessary for the force to work.
clifford
hope this helped
clifford
the friction force which oppose while it contact with surrounding. there are two kind of friction. slidding and rolling friction.
Neyaz
What is physics?
Jeuloriz Reply
physics is a branch of science in which we are dealing with the knowledge of our physical things. macroscopic as well as microscopic. we are going look inside the univers with the help of physics. you can learn nature with the help of physics. so many branches of physics you have to learn physics.
vijay
What are quarks?
Breanna Reply
6 type of quarks
Neyaz
what is candela
Akani Reply
Candela is the unit for the measurement of light intensity.
Osei
any one can prove that 1hrpower= 746 watt
Neyaz Reply
Newton second is the unit of ...............?
Neyaz
Impulse and momentum
Fauzia
force×time and mass× velocity
vijay
Good
Neyaz
What is the simple harmonic motion?
Fauzia Reply
oscillatory motion under a retarding force proportional to the amount of displacement from an equilibrium position
Yuri
Straight out of google, you could do that to, I suppose.
Yuri
*too
Yuri
ok
Fauzia
Oscillatory motion under a regarding force proportional to the amount of displacement from an equilibrium position
Neyaz
examples of work done by load of gravity
Maureen Reply
What is ehrenfest theorem?
Fauzia Reply
You can look it up, faster and more reliable answer.
Yuri
That isn't a question to ask on a forum and I also have no idea what that is.
Yuri
what is the work done by gravity on the load 87kj,11.684m,mass xkg[g=19m/s
Maureen
What is law of mass action?
Fauzia Reply
rate of chemical reactions is proportional to concentration of reactants ...
muhammad
ok thanks
Fauzia
what is lenses
Ndobe Reply
lenses are two types
Fauzia
concave and convex
muhammad
right
Fauzia
speed of light in space
Vikash Reply
in vacuum speed of light is 3×10^8 m/s
vijay
ok
Vikash
2.99×10^8m/s
Umair
2.8820^8m/s
Muhammed
which is correct answer
Vikash
he is correct but we can round up in simple terms
vijay
3×10^8m/s
vijay
is it correct
Fauzia
I mean 3*10^8 m/s ok
vijay
299792458 meter per second
babar
3*10^8m/s
Neyaz
how many Maxwell relations in thermodynamics
vijay
how we can do prove them?
vijay
What is second law of thermodynamics?
Neyaz
please who has a detailed solution to the first two professional application questions under conservation of momentum
Kwaku Reply
I want to know more about pressure
Osei
I can help
Emeh
okay go on
True
I mean on pressure
Emeh
definition of Pressure
John
it is the force per unit area of a substance.S.I unit is Pascal 1pascal is defined as 1N acting on 1m² area i.e 1pa=1N/m²
Emeh
pls explain Doppler effect
Emmex
solve this an inverted differential manometer containing oil specific gravity 0.9 and manometer reading is 400mm find the difference of pressure
Abayomi Reply
Einstine claim that nothing can go with the speed of light even its half (50%) but in to make antimatter they they hit the sub atomic particals 99.9%the speed of light how is it possible
Salima Reply
nothing with physical properties. this doesn't include things like particles and gravitational waves
Mustafa
that particles are of very small mass.... near equals to massless
Aritra
but they exist
vijay
yes they exist but mass is too less
Aritra
ok
vijay
greet all
Abayomi
the unit of radioactivity is .....?
Neyaz
Practice Key Terms 4

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Source:  OpenStax, College physics. OpenStax CNX. Jul 27, 2015 Download for free at http://legacy.cnx.org/content/col11406/1.9
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