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A magnified view of a fraction of proton is shown in an art having three quarks of spherical shape separated from each other.
Artist's conception of fractional quark charges inside a proton. A group of three quark charges add up to the single positive charge on the proton: 1 3 q e + 2 3 q e + 2 3 q e = +1 q e .

Separation of charge in atoms

Charges in atoms and molecules can be separated—for example, by rubbing materials together. Some atoms and molecules have a greater affinity for electrons than others and will become negatively charged by close contact in rubbing, leaving the other material positively charged. (See [link] .) Positive charge can similarly be induced by rubbing. Methods other than rubbing can also separate charges. Batteries, for example, use combinations of substances that interact in such a way as to separate charges. Chemical interactions may transfer negative charge from one substance to the other, making one battery terminal negative and leaving the first one positive.

When materials are rubbed together, charges can be separated, particularly if one material has a greater affinity for electrons than another. (a) Both the amber and cloth are originally neutral, with equal positive and negative charges. Only a tiny fraction of the charges are involved, and only a few of them are shown here. (b) When rubbed together, some negative charge is transferred to the amber, leaving the cloth with a net positive charge. (c) When separated, the amber and cloth now have net charges, but the absolute value of the net positive and negative charges will be equal.

No charge is actually created or destroyed when charges are separated as we have been discussing. Rather, existing charges are moved about. In fact, in all situations the total amount of charge is always constant. This universally obeyed law of nature is called the law of conservation of charge    .

Law of conservation of charge

Total charge is constant in any process.

Making connections: net charge

Hence if a closed system is neutral, it will remain neutral. Similarly, if a closed system has a charge, say, −10 e , it will always have that charge. The only way to change the charge of a system is to transfer charge outside, either by bringing in charge or removing charge. If it is possible to transfer charge outside, the system is no longer closed/isolated and is known as an open system. However, charge is always conserved, for both open and closed systems. Consequently, the charge transferred to/from an open system is equal to the change in the system's charge.

For example, each of the two materials (amber and cloth) discussed in [link] have no net charge initially. The only way to change their charge is to transfer charge from outside each object. When they are rubbed together, negative charge is transferred to the amber and the final charge of the amber is the sum of the initial charge and the charge transferred to it. On the other hand, the final charge on the cloth is equal to its initial charge minus the charge transferred out.

Similarly when glass is rubbed with silk, the net charge on the silk is its initial charge plus the incoming charge and the charge on the glass is the initial charge minus the outgoing charge. Also the charge gained by the silk will be equal to the charge lost by the glass, which means that if the silk gains –5 e charge, the glass would have lost −5 e charge.

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Source:  OpenStax, College physics for ap® courses. OpenStax CNX. Nov 04, 2016 Download for free at https://legacy.cnx.org/content/col11844/1.14
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