<< Chapter < Page Chapter >> Page >

But there are limits to Bohr’s theory. It cannot be applied to multielectron atoms, even one as simple as a two-electron helium atom. Bohr’s model is what we call semiclassical . The orbits are quantized (nonclassical) but are assumed to be simple circular paths (classical). As quantum mechanics was developed, it became clear that there are no well-defined orbits; rather, there are clouds of probability. Bohr’s theory also did not explain that some spectral lines are doublets (split into two) when examined closely. We shall examine many of these aspects of quantum mechanics in more detail, but it should be kept in mind that Bohr did not fail. Rather, he made very important steps along the path to greater knowledge and laid the foundation for all of atomic physics that has since evolved.

Phet explorations: models of the hydrogen atom

How did scientists figure out the structure of atoms without looking at them? Try out different models by shooting light at the atom. Check how the prediction of the model matches the experimental results.

Models of the Hydrogen Atom

Section summary

  • The planetary model of the atom pictures electrons orbiting the nucleus in the way that planets orbit the sun. Bohr used the planetary model to develop the first reasonable theory of hydrogen, the simplest atom. Atomic and molecular spectra are quantized, with hydrogen spectrum wavelengths given by the formula
    1 λ = R 1 n f 2 1 n i 2 , size 12{ { {1} over {λ} } =R left ( { {1} over {n rSub { size 8{f} } rSup { size 8{2} } } } - { {1} over {n rSub { size 8{i} } rSup { size 8{2} } } } right )} {}
    where λ size 12{λ} {} is the wavelength of the emitted EM radiation and R size 12{R} {} is the Rydberg constant, which has the value
    R = 1.097 × 10 7 m −1 .
  • The constants n i size 12{n rSub { size 8{i} } } {} and n f size 12{n rSub { size 8{f} } } {} are positive integers, and n i must be greater than n f size 12{n rSub { size 8{f} } } {} .
  • Bohr correctly proposed that the energy and radii of the orbits of electrons in atoms are quantized, with energy for transitions between orbits given by
    Δ E = hf = E i E f , size 12{ΔE= ital "hf"=E rSub { size 8{i} } - E rSub { size 8{f} } } {}
    where Δ E size 12{ΔE} {} is the change in energy between the initial and final orbits and hf size 12{ ital "hf"} {} is the energy of an absorbed or emitted photon. It is useful to plot orbital energies on a vertical graph called an energy-level diagram.
  • Bohr proposed that the allowed orbits are circular and must have quantized orbital angular momentum given by
    L = m e vr n = n h 2 π n = 1, 2, 3 … ,
    where L size 12{L} {} is the angular momentum, r n size 12{r rSub { size 8{n} } } {} is the radius of the n th size 12{n"th"} {} orbit, and h size 12{h} {} is Planck’s constant. For all one-electron (hydrogen-like) atoms, the radius of an orbit is given by
    r n = n 2 Z a B (allowed orbits n = 1, 2, 3, ...),
    Z size 12{Z} {} is the atomic number of an element (the number of electrons is has when neutral) and a B size 12{a rSub { size 8{B} } } {} is defined to be the Bohr radius, which is
    a B = h 2 4 π 2 m e kq e 2 = 0.529 × 10 10 m . size 12{a rSub { size 8{B} } = { {h rSup { size 8{2} } } over {4π rSup { size 8{2} } m rSub { size 8{e} } ital "kq" rSub { size 8{e} } rSup { size 8{2} } } } =0 "." "529" times "10" rSup { size 8{ - "10"} } " m" "." } {}
  • Furthermore, the energies of hydrogen-like atoms are given by
    E n = Z 2 n 2 E 0 n = 1, 2, 3 ... , size 12{ left (n=1, 2, 3 "." "." "." right )} {}
    where E 0 size 12{E rSub { size 8{0} } } {} is the ground-state energy and is given by
    E 0 = 2 q e 4 m e k 2 h 2 = 13.6 eV. size 12{E rSub { size 8{0} } = { {2π rSup { size 8{2} } q rSub { size 8{e} } rSup { size 8{4} } m rSub { size 8{e} } k rSup { size 8{2} } } over {h rSup { size 8{2} } } } ="13" "." 6" eV"} {}
    Thus, for hydrogen,
    E n = 13.6 eV n 2 size 12{E rSub { size 8{n} } = - { {"13" "." 6" eV"} over {n rSup { size 8{2} } } } } {} n = 1, 2, 3 ... . size 12{ left (n=1, 2, 3 "." "." "." right ) "." } {}
  • The Bohr Theory gives accurate values for the energy levels in hydrogen-like atoms, but it has been improved upon in several respects.

Conceptual questions

How do the allowed orbits for electrons in atoms differ from the allowed orbits for planets around the sun? Explain how the correspondence principle applies here.

Got questions? Get instant answers now!

Questions & Answers

and yea about that hypothesis thing....For electrons and photons and other microscopic particles ...The dual nature applicable but Macroscopic object follows De Broglie's Hypothesis or Theory
Bibekbir Reply
Duh !! And guys I can't see any conversation! All I can guess what is going on ,on board is through notifications ! otherwise this screen is blank ! Does anybody know what is happening ?
Bibekbir
I am facing problem ....I am not able to view the latest conversation in group discussion. ..its just showing a blank page even after reinstalling the app...although the Internet connection is also working
Bibekbir
its ok
Salima
Therefore it was summarised that electrons or any particle for instance (*De Broglie's hypothesis ) shows Dual nature
Bibekbir Reply
ok i get it but it is still a hypothesis
Salima
can i ask qusetions sometimes
Salima
yup it was as if electrons knew they were being watched ...
Bibekbir Reply
Which I personally find very creepy !
Bibekbir
Which I personally find very creepy !
Bibekbir
it is creepy
Salima
Which confused scientists so much ...so tried the same experiment using a microscope this time to watch the motion of the electrons...and surprisingly this time two slits were formed. !
Bibekbir Reply
really
Salima
Well what common sense says is ...There will be two slits on photographic plate...
Bibekbir Reply
But what was observed was totally unexpected. ..There were wave like imprint on the photographic plate....like water waves...
Bibekbir
ok then...
Salima
Well to explain the dual nature of light ...We need to study Young's double slit experiment .In which,.. okay I want you to imagine I have gun loaded with electrons. ..and before me I have this sheet with two slit in it and behind this sheet a photographic plate. .....what do you think my observation will be ?
Bibekbir Reply
can't say anything
Salima
Well light can exist as wave as well as a particle....There is something called Dual nature of light
Bibekbir Reply
yes you got it
Ahmad
i know about it but how is it possible
Salima
it depends upon given condition to photon
Ahmad
here is answer about that
Bashir
here is no answer about that
Bashir
Mr. Bashir there is no question that have no answer
Salima
ok
Bashir
Why the Big Bang create more matter then antimatter?
Salima Reply
there are a few theories but it is still mostly a mystery
James
Is it possible that the whole concept of antimatter is wrong after all its just theories
Salima
no its not theory
ghulam
but there is no strong evidence about it they are trying to make antimatter what if they are searching for, turns out something different other then antimatter
Salima
half of physics does not consists of the strong evidence
ghulam
salima are you pakistani ?
ghulam
yeah
Salima
I read in class 10th
Salima
And i am not talking about evidence
Salima
Actually there is an evidence .....its called cosmic inflation. ..
Bibekbir
can you explain
Salima
sure
Bibekbir
It's like this....okay imagine for a second that all the galaxies and stars ...and planet with all their energies vanishes
Bibekbir
please explain
Salima
even the black holes dark matter and dark energies also vanishes...
Bibekbir
Can anyone tell me what should be left ?
Bibekbir
ok
Salima
nothing but space
Salima
You will say an empty void ...but that's not the case after this called universe mapping we got this an active energetic background ! which was expanding at a very fast rate
Bibekbir
Now if something is expanding at a speed of nearly speed of light !! then it must have stated from a very small sized object and there you have big bang theory
Bibekbir
yeah i get it
Salima
You will say a void right ? But that was not what mathematical calculations said ....even there is something called universe mapping which mapped the energies in this background. ... and we found that this universe as whole itself was increasing with the speed faster than light !!!
Bibekbir
faster then light!!!
Salima
interesting question. would love a proper explanation.
Beatrax
questions are always intersting only if you know the answer
Salima
or understand the question
Salima
yup faster than light ...now here some people will ask that Einstein had claimed nothing can be faster than light right ? ....but the Universe doesn't count in 'nothing ' and everything is in universe including light ...
Bibekbir
Beatrax do you have a question?
Bibekbir
universe is expending right so there must be a limit for its expension and after that would it be possible that it start contracting again?
Salima
Well we simply don't know to what universe is expanding to .....so here comes string theory....which is story of another time though. ... yes there is a theory though which claims that the universe will again collapse in a small mass just as it started in big bang
Bibekbir
so we can say that big bang will happen again
Salima
Let's come back to your question on antimatter right ? ....well we simply don't have a lot of information about anti matter...though there is a theory which claims that at the time of big bang antimatter was made with matter ....but not in the same quantity. ..
Bibekbir
Because if it were to happen .....The matter won't simply exist ...but we know it does exist....
Bibekbir
there must be some reason that why it creat more matter
Salima
and no the concept of antimatter is NOT wrong!!! Don't ever say that !!! Because some scientists spent their whole life studying on this .....and you will be surprised to know that there are antimatter found on the exosphere of Earth.
Bibekbir
and Ghulam you wrong there Bro. ..70% of physics is mathematics.....which language of universe....which is kinda right every time. ..Einstein gave all his theory solely based on thoughts and mathematics...
Bibekbir
really how is it possible was it natural i know that they are making antimatter but i don't believe it
Salima
And before something become a solid point ... ..It has to go through a long process of scientists in panels and all those stuff. ....and surprisingly it's all observable phenomenons....so yeah physics is actually defination of logic....mind that ..
Bibekbir
Do anyone have any question? feel free to ask ...
Bibekbir
yeah i also think that physics is the basic of all the universe and every thing we see in it
Salima
oh yeah i will
Salima
Yeah we kinda don't know....a lot on this ....moreover....I have not been keeping tap on this topic....so maybe they have got some stuff up their sleeves but I just don't know...
Bibekbir
what is actully light photons or electromagnetic waves
Salima
Well main topic which I focus on is dark matter dark energy and exoplanets. ..
Bibekbir
and maybe little bit of quantum mechanics
Bibekbir
ah there good question !! very good question! !
Bibekbir
are you a student of physics and where are you from
Salima
thanks
Salima
okay now ....We don't only have proton electron and neutron duh ! that's what students are taught!
Bibekbir
Actually from CERN till now 35 subatomic particles have been found !!!
Bibekbir
and now let's come back to your question about what is light photons....I guess you all from 12th grade am I right ?
Bibekbir
oh whats the 35 subatomic particals
Salima
no actully 10th grade
Salima
What? I am actually umm. ...In my first year of college ....Sem1 so yea I am 18 years old....and I am doing undergraduate course in Maths Chemistry and Physics ... I am from India ! Duh ! I thought my name would give away my nationality !
Bibekbir
There are a lot of those subatomic particles like higgs boson particle is one of them
Bibekbir
oh
Salima
Not a lot 35
Bibekbir
i am physics professor any problm dear friend
ghulam
oh what about my question
Salima
Salima you know a lot according to your age. ...don't worry you have a while chapter in 11th and 12th physics in electromagnetic waves and light photon ....
Bibekbir
*whole
Bibekbir
i am 16 years old
Salima
Mr. Ghulam No hard feelings I just said what I felt right . And I just love physics a lot can't just read any bad comment about it.Again I said what I felt right. If you are offended by anything I said Sir,then I am sorry . I am not here offend anyone,.just give my honest answers andwhatever I study
Bibekbir
Mr.Ghulam are you a Pakistani
Salima
why physics is more difficult for commerce student?
Bashir
i am a fsc pre medical student
Sameer
hello
James
am james
James
physics is not difficult but when you don't have any interest it seems difficult
Salima
James can you tell us about big bang theory?
Bashir
Bashir you can read it in above comments
Salima
Yes but is very necessary for us but how to understand that cause our direction is another side
Bashir
hi Bibekbir are you there
Salima
stay on your direction Mr. Bashir
Salima
Yes
Bashir
can anyone answer my question?
Salima
Yes can but ..
Bashir
but..
Salima
i just want answer not "but"
Salima
Ok you can ask
Bashir
?
Bashir
what light actually photon or electromagnetic waves
Salima
Both
Ahmad
how? can a partical be wave at the same time
Salima
yes photon depend upon condition
Ahmad
photon is the energy packet ..light consist of photons in the form of EM waves
ghulam
What is the difference between potential difference and electromotive force
Neba Reply
basically potentiometer is series circuit or parallel circuit?
muhammad Reply
What is half-life
Godwin Reply
the life in which half of the radioactive element decay
Arif
what is fluid
Anthony Reply
anything that flows is Liquid.
prakash
a substance that has no specific shape
Saleemulhaq
How submarines floats one water the same time sink in water
Courage Reply
A submarine has the ability to float and sink. The ability to control buoyancy comes from the submarine'strim or ballast tanks which can be filled with either water or air, depending on whether the submarine needs to floator sink. When the submarine floats it means its trim tanks are filled with air
Arif
define electromagnetic radiation
Anthony
what is work
Ojo Reply
Force times distance
Karanja
product of force and distance...
Arif
Is physics a natural science?
Adebisi Reply
Nature is all physics
Salima
Practice Key Terms 7

Get the best College physics course in your pocket!





Source:  OpenStax, College physics. OpenStax CNX. Jul 27, 2015 Download for free at http://legacy.cnx.org/content/col11406/1.9
Google Play and the Google Play logo are trademarks of Google Inc.

Notification Switch

Would you like to follow the 'College physics' conversation and receive update notifications?

Ask