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Because many solvents also have protons present, their use in obtaining NMR spectra is problematic. The signal due to the protons in a typical organic solvent would be so large that it would swamp any signal due to the sample you want to measure - sort of like trying to see a tiny flashlight in broad daylight outdoors. In order to remedy this problem, one could choose solvents which do not have protons such as CS 2 size 12{ ital "CS" rSub { size 8{2} } } {} or CCl 4 size 12{ ital "CCl" rSub { size 8{4} } } {} ; however, these are not suitable solvents for modern FT spectrometers. A better solution is to use solvents in which the protons have been replaced by deuterium. Such solvents, known as deuterated solvents, have very similar properties to their proton-analogues. Thus deuterated benzene is very similar to normal benzene. While deuterium does have a spin (spin = 1), the frequency at which the deuterium nucleus resonates in a magnetic field is sufficiently different from that of protons so that its presence does not interfere with the detection of proton signals. In reality, not all protons of a solvent are replaced in deuterated solvents such that a residual peak due to the presence of a small quantity of protons can usually be observed. This peak usually serves as a good reference point for determining the chemical shifts of peaks in the sample since the peak locations of common deuterated solvents are well known. One can also add a small amount of TMS [tetramethylsilene, Si ( CH 3 ) 4 size 12{ ital "Si" \( ital "CH" rSub { size 8{3} } \) rSub { size 8{4} } } {} ] to the sample and use its peak to serve as a reference peak as well.

Table 2. Some commonly used deuterated solvents.

d-chloroform CDCl 3 size 12{ ital "CDCl" rSub { size 8{3} } } {}
d 6 size 12{d rSub { size 8{6} } } {} -benzene C 6 D 6 size 12{C rSub { size 8{6} } D rSub { size 8{6} } } {}
d 3 size 12{d rSub { size 8{3} } } {} -acetonitrile CD 3 CN size 12{ ital "CD" rSub { size 8{3} } ital "CN"} {}
d 6 size 12{d rSub { size 8{6} } } {} -acetone CD 3 C ( = O ) CD 3 size 12{ ital "CD" rSub { size 8{3} } C \( =O \) ital "CD" rSub { size 8{3} } } {}
d 4 size 12{d rSub { size 8{4} } } {} -methanol CD 3 OD size 12{ ital "CD" rSub { size 8{3} } ital "OD"} {}
d 8 size 12{d rSub { size 8{8} } } {} -toluene C 6 D 5 CD 3 size 12{C rSub { size 8{6} } D rSub { size 8{5} } ital "CD" rSub { size 8{3} } } {}
d 2 size 12{d rSub { size 8{2} } } {} -dichloromethane CD 2 Cl 2 size 12{ ital "CD" rSub { size 8{2} } ital "Cl" rSub { size 8{2} } } {}
deuterated water D 2 O size 12{D rSub { size 8{2} } O} {}
In order to obtain really high field strengths, special magnets have been built of materials that are kept at liquid helium temperatures such that they become superconducting. Typically field strengths of 200, 300, 400, and 500 MHz are commonly employed. Instruments are even being built with field strengths as high as 900 MHz!!! The choice of field strength depends upon the sample and bigger is usually, but not always, better.

Because the field strengths are so high, it is potentially dangerous for persons with pacemakers to enter into the fringe field region of these magnets. The magnets will also erase the magnetic information stored on IDs and credit cards. The stronger magnets have been known to pull heavy tools up into them if someone with tools walks too close to the magnet. This often causes severe damage to the magnet.

In this set of exercises, we are going to concentrate on 1 H size 12{ {} rSup { size 8{1} } H} {} NMR spectroscopy since it is the most widely used and simplest of the NMR-active nuclei to discuss.

Chemical shift

Since the effect being measured involves the measurement of spin states of a nucleus, the values of Δ size 12{Δ} {} E will be affected by the local magnetic field of a nucleus being examined.

The local magnetic field is, in turn, affected by the chemical environment of the nucleus. Δ size 12{Δ} {} E thus becomes a measure of the chemical environment of the nucleus. Hydrogen atoms bonded to sp 3 size 12{ ital "sp" rSup { size 8{3} } } {} carbon atoms are found in different regions of the NMR spectrum from hydrogen atoms attached to alkene sp 2 size 12{ ital "sp" rSup { size 8{2} } } {} carbon atoms, alkyne sp carbon atoms, and aromatic sp 2 size 12{ ital "sp" rSup { size 8{2} } } {} carbon atoms, oxygen, nitrogen, metals, etc.

Questions & Answers

how do they get the third part x = (32)5/4
kinnecy Reply
can someone help me with some logarithmic and exponential equations.
Jeffrey Reply
sure. what is your question?
okay, so you have 6 raised to the power of 2. what is that part of your answer
I don't understand what the A with approx sign and the boxed x mean
it think it's written 20/(X-6)^2 so it's 20 divided by X-6 squared
I'm not sure why it wrote it the other way
I got X =-6
ok. so take the square root of both sides, now you have plus or minus the square root of 20= x-6
oops. ignore that.
so you not have an equal sign anywhere in the original equation?
Commplementary angles
Idrissa Reply
im all ears I need to learn
right! what he said ⤴⤴⤴
what is a good calculator for all algebra; would a Casio fx 260 work with all algebra equations? please name the cheapest, thanks.
Kevin Reply
a perfect square v²+2v+_
Dearan Reply
kkk nice
Abdirahman Reply
algebra 2 Inequalities:If equation 2 = 0 it is an open set?
Kim Reply
or infinite solutions?
The answer is neither. The function, 2 = 0 cannot exist. Hence, the function is undefined.
Embra Reply
if |A| not equal to 0 and order of A is n prove that adj (adj A = |A|
Nancy Reply
rolling four fair dice and getting an even number an all four dice
ramon Reply
Kristine 2*2*2=8
Bridget Reply
Differences Between Laspeyres and Paasche Indices
Emedobi Reply
No. 7x -4y is simplified from 4x + (3y + 3x) -7y
Mary Reply
is it 3×y ?
Joan Reply
J, combine like terms 7x-4y
Bridget Reply
how do you translate this in Algebraic Expressions
linda Reply
Need to simplify the expresin. 3/7 (x+y)-1/7 (x-1)=
Crystal Reply
. After 3 months on a diet, Lisa had lost 12% of her original weight. She lost 21 pounds. What was Lisa's original weight?
Chris Reply
what's the easiest and fastest way to the synthesize AgNP?
Damian Reply
types of nano material
abeetha Reply
I start with an easy one. carbon nanotubes woven into a long filament like a string
many many of nanotubes
what is the k.e before it land
what is the function of carbon nanotubes?
I'm interested in nanotube
what is nanomaterials​ and their applications of sensors.
Ramkumar Reply
what is nano technology
Sravani Reply
what is system testing?
preparation of nanomaterial
Victor Reply
Yes, Nanotechnology has a very fast field of applications and their is always something new to do with it...
Himanshu Reply
good afternoon madam
what is system testing
what is the application of nanotechnology?
In this morden time nanotechnology used in many field . 1-Electronics-manufacturad IC ,RAM,MRAM,solar panel etc 2-Helth and Medical-Nanomedicine,Drug Dilivery for cancer treatment etc 3- Atomobile -MEMS, Coating on car etc. and may other field for details you can check at Google
anybody can imagine what will be happen after 100 years from now in nano tech world
after 100 year this will be not nanotechnology maybe this technology name will be change . maybe aftet 100 year . we work on electron lable practically about its properties and behaviour by the different instruments
name doesn't matter , whatever it will be change... I'm taking about effect on circumstances of the microscopic world
how hard could it be to apply nanotechnology against viral infections such HIV or Ebola?
silver nanoparticles could handle the job?
not now but maybe in future only AgNP maybe any other nanomaterials
I'm interested in Nanotube
this technology will not going on for the long time , so I'm thinking about femtotechnology 10^-15
can nanotechnology change the direction of the face of the world
Prasenjit Reply
At high concentrations (>0.01 M), the relation between absorptivity coefficient and absorbance is no longer linear. This is due to the electrostatic interactions between the quantum dots in close proximity. If the concentration of the solution is high, another effect that is seen is the scattering of light from the large number of quantum dots. This assumption only works at low concentrations of the analyte. Presence of stray light.
Ali Reply
the Beer law works very well for dilute solutions but fails for very high concentrations. why?
bamidele Reply
how did you get the value of 2000N.What calculations are needed to arrive at it
Smarajit Reply
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Source:  OpenStax, Chem 215 spring08. OpenStax CNX. Mar 21, 2008 Download for free at http://cnx.org/content/col10496/1.8
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