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By the end of this section, you will be able to:
  • Describe the types of intermolecular forces possible between atoms or molecules in condensed phases (dispersion forces, dipole-dipole attractions, and hydrogen bonding)
  • Identify the types of intermolecular forces experienced by specific molecules based on their structures
  • Explain the relation between the intermolecular forces present within a substance and the temperatures associated with changes in its physical state

As was the case for gaseous substances, the kinetic molecular theory may be used to explain the behavior of solids and liquids. In the following description, the term particle will be used to refer to an atom, molecule, or ion. Note that we will use the popular phrase “intermolecular attraction” to refer to attractive forces between the particles of a substance, regardless of whether these particles are molecules, atoms, or ions.

Consider these two aspects of the molecular-level environments in solid, liquid, and gaseous matter:

  • Particles in a solid are tightly packed together and often arranged in a regular pattern; in a liquid, they are close together with no regular arrangement; in a gas, they are far apart with no regular arrangement.
  • Particles in a solid vibrate about fixed positions and do not generally move in relation to one another; in a liquid, they move past each other but remain in essentially constant contact; in a gas, they move independently of one another except when they collide.

The differences in the properties of a solid, liquid, or gas reflect the strengths of the attractive forces between the atoms, molecules, or ions that make up each phase. The phase in which a substance exists depends on the relative extents of its intermolecular forces (IMFs) and the kinetic energies (KE) of its molecules. IMFs are the various forces of attraction that may exist between the atoms and molecules of a substance due to electrostatic phenomena, as will be detailed in this module. These forces serve to hold particles close together, whereas the particles’ KE provides the energy required to overcome the attractive forces and thus increase the distance between particles. [link] illustrates how changes in physical state may be induced by changing the temperature, hence, the average KE, of a given substance.

Three sealed flasks are labeled, “Crystalline solid,” “Liquid,” and “Gas,” from left to right. The first flask holds a cube composed of small spheres sitting on the bottom while the second flask shows a lot of small spheres in the bottom that are spaced a small distance apart from one another and have lines around them to indicate motion. The third flask shows a few spheres spread far from one another with larger lines to indicate motion. There is a right-facing arrow that spans the top of all three flasks. The arrow is labeled, “Increasing K E ( temperature ).” There is a left-facing arrow that spans the bottom of all three flasks. The arrow is labeled, “Increasing I M F.”
Transitions between solid, liquid, and gaseous states of a substance occur when conditions of temperature or pressure favor the associated changes in intermolecular forces. (Note: The space between particles in the gas phase is much greater than shown.)

As an example of the processes depicted in this figure, consider a sample of water. When gaseous water is cooled sufficiently, the attractions between H 2 O molecules will be capable of holding them together when they come into contact with each other; the gas condenses, forming liquid H 2 O. For example, liquid water forms on the outside of a cold glass as the water vapor in the air is cooled by the cold glass, as seen in [link] .

Image a shows a brown colored beverage in a glass with condensation on the outside. Image b shows a body of water with fog hovering above the surface of the water.
Condensation forms when water vapor in the air is cooled enough to form liquid water, such as (a) on the outside of a cold beverage glass or (b) in the form of fog. (credit a: modification of work by Jenny Downing; credit b: modification of work by Cory Zanker)

Questions & Answers

Do somebody tell me a best nano engineering book for beginners?
s. Reply
what is fullerene does it is used to make bukky balls
Devang Reply
are you nano engineer ?
s.
what is the Synthesis, properties,and applications of carbon nano chemistry
Abhijith Reply
so some one know about replacing silicon atom with phosphorous in semiconductors device?
s. Reply
Yeah, it is a pain to say the least. You basically have to heat the substarte up to around 1000 degrees celcius then pass phosphene gas over top of it, which is explosive and toxic by the way, under very low pressure.
Harper
how to fabricate graphene ink ?
SUYASH Reply
for screen printed electrodes ?
SUYASH
What is lattice structure?
s. Reply
of graphene you mean?
Ebrahim
or in general
Ebrahim
in general
s.
Graphene has a hexagonal structure
tahir
On having this app for quite a bit time, Haven't realised there's a chat room in it.
Cied
what is biological synthesis of nanoparticles
Sanket Reply
what's the easiest and fastest way to the synthesize AgNP?
Damian Reply
China
Cied
types of nano material
abeetha Reply
I start with an easy one. carbon nanotubes woven into a long filament like a string
Porter
many many of nanotubes
Porter
what is the k.e before it land
Yasmin
what is the function of carbon nanotubes?
Cesar
I'm interested in nanotube
Uday
what is nanomaterials​ and their applications of sensors.
Ramkumar Reply
what is nano technology
Sravani Reply
what is system testing?
AMJAD
preparation of nanomaterial
Victor Reply
Yes, Nanotechnology has a very fast field of applications and their is always something new to do with it...
Himanshu Reply
good afternoon madam
AMJAD
what is system testing
AMJAD
what is the application of nanotechnology?
Stotaw
In this morden time nanotechnology used in many field . 1-Electronics-manufacturad IC ,RAM,MRAM,solar panel etc 2-Helth and Medical-Nanomedicine,Drug Dilivery for cancer treatment etc 3- Atomobile -MEMS, Coating on car etc. and may other field for details you can check at Google
Azam
anybody can imagine what will be happen after 100 years from now in nano tech world
Prasenjit
after 100 year this will be not nanotechnology maybe this technology name will be change . maybe aftet 100 year . we work on electron lable practically about its properties and behaviour by the different instruments
Azam
name doesn't matter , whatever it will be change... I'm taking about effect on circumstances of the microscopic world
Prasenjit
how hard could it be to apply nanotechnology against viral infections such HIV or Ebola?
Damian
silver nanoparticles could handle the job?
Damian
not now but maybe in future only AgNP maybe any other nanomaterials
Azam
Hello
Uday
I'm interested in Nanotube
Uday
this technology will not going on for the long time , so I'm thinking about femtotechnology 10^-15
Prasenjit
can nanotechnology change the direction of the face of the world
Prasenjit Reply
At high concentrations (>0.01 M), the relation between absorptivity coefficient and absorbance is no longer linear. This is due to the electrostatic interactions between the quantum dots in close proximity. If the concentration of the solution is high, another effect that is seen is the scattering of light from the large number of quantum dots. This assumption only works at low concentrations of the analyte. Presence of stray light.
Ali Reply
how did you get the value of 2000N.What calculations are needed to arrive at it
Smarajit Reply
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how do you find theWhat are the wavelengths and energies per photon of two lines
caroline Reply
The eyes of some reptiles are sensitive to 850 nm light. If the minimum energy to trigger the receptor at this wavelength is 3.15 x 10-14 J, what is the minimum number of 850 nm photons that must hit the receptor in order for it to be triggered?
razzyd Reply
A teaspoon of the carbohydrate sucrose contains 16 calories, what is the mass of one teaspoo of sucrose if the average number of calories for carbohydrate is 4.1 calories/g?
ifunanya Reply
4. On the basis of dipole moments and/or hydrogen bonding, explain in a qualitative way the differences in the boiling points of acetone (56.2 °C) and 1-propanol (97.4 °C), which have similar molar masses
Kyndall Reply
Calculate the bond order for an ion with this configuration: (?2s)2(??2s)2(?2px)2(?2py,?2pz)4(??2py,??2pz)3
Gabe Reply
Which of the following will increase the percent of HF that is converted to the fluoride ion in water? (a) addition of NaOH (b) addition of HCl (c) addition of NaF
Tarun Reply
Practice Key Terms 8

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Source:  OpenStax, Ut austin - principles of chemistry. OpenStax CNX. Mar 31, 2016 Download for free at http://legacy.cnx.org/content/col11830/1.13
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