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[link] is a schematic representation of the two fundamental parts of any voltage source. The emf (represented by a script E in the figure) and internal resistance r size 12{r} {} are in series. The smaller the internal resistance for a given emf, the more current and the more power the source can supply.

This diagram shows a battery with a schematic indicating the e m f, represented by script E, and the internal resistance r of the battery. The voltage output of the battery is measured between the input and output terminals and is equal to the e m f minus the product of the current and the internal resistance.
Any voltage source (in this case, a carbon-zinc dry cell) has an emf related to its source of potential difference, and an internal resistance r size 12{r} {} related to its construction. (Note that the script E stands for emf.). Also shown are the output terminals across which the terminal voltage V size 12{V} {} is measured. Since V = emf Ir size 12{V="emf" - ital "Ir"} {} , terminal voltage equals emf only if there is no current flowing.

The internal resistance r size 12{r} {} can behave in complex ways. As noted, r size 12{r} {} increases as a battery is depleted. But internal resistance may also depend on the magnitude and direction of the current through a voltage source, its temperature, and even its history. The internal resistance of rechargeable nickel-cadmium cells, for example, depends on how many times and how deeply they have been depleted.

Things great and small: the submicroscopic origin of battery potential

Various types of batteries are available, with emfs determined by the combination of chemicals involved. We can view this as a molecular reaction (what much of chemistry is about) that separates charge.

The lead-acid battery used in cars and other vehicles is one of the most common types. A single cell (one of six) of this battery is seen in [link] . The cathode (positive) terminal of the cell is connected to a lead oxide plate, while the anode (negative) terminal is connected to a lead plate. Both plates are immersed in sulfuric acid, the electrolyte for the system.

A simplified view of a battery shows a rectangular container of sulfuric acid with two thin upright metal plates immersed in it, one made of lead and the other made of lead oxide. Each plate projects above the liquid line, providing a positive or negative terminal above the battery. The positive terminal is labeled as the cathode, and the negative terminal is labeled as the anode.
Artist’s conception of a lead-acid cell. Chemical reactions in a lead-acid cell separate charge, sending negative charge to the anode, which is connected to the lead plates. The lead oxide plates are connected to the positive or cathode terminal of the cell. Sulfuric acid conducts the charge as well as participating in the chemical reaction.

The details of the chemical reaction are left to the reader to pursue in a chemistry text, but their results at the molecular level help explain the potential created by the battery. [link] shows the result of a single chemical reaction. Two electrons are placed on the anode, making it negative, provided that the cathode supplied two electrons. This leaves the cathode positively charged, because it has lost two electrons. In short, a separation of charge has been driven by a chemical reaction.

Note that the reaction will not take place unless there is a complete circuit to allow two electrons to be supplied to the cathode. Under many circumstances, these electrons come from the anode, flow through a resistance, and return to the cathode. Note also that since the chemical reactions involve substances with resistance, it is not possible to create the emf without an internal resistance.

The diagram shows a simplified view of a battery depicting a rectangular container containing two thin upright metal plates immersed in a liquid. An enlarged view of the metal plates is also shown. One plate has positive charges on it shown as small spheres enclosing a positive sign. The other plate has negative charge on it shown as small spheres enclosing an electron. The electrons are shown to move from the positive plate to the negative plate using arrows through a molecular reaction in the liquid.
Artist’s conception of two electrons being forced onto the anode of a cell and two electrons being removed from the cathode of the cell. The chemical reaction in a lead-acid battery places two electrons on the anode and removes two from the cathode. It requires a closed circuit to proceed, since the two electrons must be supplied to the cathode.

Questions & Answers

what does nano mean?
Anassong Reply
nano basically means 10^(-9). nanometer is a unit to measure length.
Bharti
do you think it's worthwhile in the long term to study the effects and possibilities of nanotechnology on viral treatment?
Damian Reply
absolutely yes
Daniel
how to know photocatalytic properties of tio2 nanoparticles...what to do now
Akash Reply
it is a goid question and i want to know the answer as well
Maciej
characteristics of micro business
Abigail
for teaching engĺish at school how nano technology help us
Anassong
Do somebody tell me a best nano engineering book for beginners?
s. Reply
what is fullerene does it is used to make bukky balls
Devang Reply
are you nano engineer ?
s.
fullerene is a bucky ball aka Carbon 60 molecule. It was name by the architect Fuller. He design the geodesic dome. it resembles a soccer ball.
Tarell
what is the actual application of fullerenes nowadays?
Damian
That is a great question Damian. best way to answer that question is to Google it. there are hundreds of applications for buck minister fullerenes, from medical to aerospace. you can also find plenty of research papers that will give you great detail on the potential applications of fullerenes.
Tarell
what is the Synthesis, properties,and applications of carbon nano chemistry
Abhijith Reply
Mostly, they use nano carbon for electronics and for materials to be strengthened.
Virgil
is Bucky paper clear?
CYNTHIA
so some one know about replacing silicon atom with phosphorous in semiconductors device?
s. Reply
Yeah, it is a pain to say the least. You basically have to heat the substarte up to around 1000 degrees celcius then pass phosphene gas over top of it, which is explosive and toxic by the way, under very low pressure.
Harper
Do you know which machine is used to that process?
s.
how to fabricate graphene ink ?
SUYASH Reply
for screen printed electrodes ?
SUYASH
What is lattice structure?
s. Reply
of graphene you mean?
Ebrahim
or in general
Ebrahim
in general
s.
Graphene has a hexagonal structure
tahir
On having this app for quite a bit time, Haven't realised there's a chat room in it.
Cied
what is biological synthesis of nanoparticles
Sanket Reply
what's the easiest and fastest way to the synthesize AgNP?
Damian Reply
China
Cied
types of nano material
abeetha Reply
I start with an easy one. carbon nanotubes woven into a long filament like a string
Porter
many many of nanotubes
Porter
what is the k.e before it land
Yasmin
what is the function of carbon nanotubes?
Cesar
I'm interested in nanotube
Uday
what is nanomaterials​ and their applications of sensors.
Ramkumar Reply
what is nano technology
Sravani Reply
what is system testing?
AMJAD
preparation of nanomaterial
Victor Reply
how did you get the value of 2000N.What calculations are needed to arrive at it
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Source:  OpenStax, College physics ii. OpenStax CNX. Nov 29, 2012 Download for free at http://legacy.cnx.org/content/col11458/1.2
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