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The kinetic theory of matter

The kinetic theory of matter helps us to explain why matter exists in different phases (i.e. solid, liquid and gas), and how matter can change from one phase to the next. The kinetic theory of matter also helpsus to understand other properties of matter. It is important to realise that what we will go on to describe is only a theory . It cannot be proved beyond doubt, but the fact that it helps us to explain our observations of changes in phase, and otherproperties of matter, suggests that it probably is more than just a theory.

Broadly, the Kinetic Theory of Matter says that:

  • Matter is made up of particles that are constantly moving.
  • All particles have energy , but the energy varies depending on whether the substance is a solid, liquid or gas. Solid particles have the least amount ofenergy and gas particles have the greatest amount of energy.
  • The temperature of a substance is a measure of the average kinetic energy of the particles.
  • A change in phase may occur when the energy of the particles is changed.
  • There are spaces between the particles of matter.
  • There are attractive forces between particles and these become stronger as the particles move closer together. These attractive forces will either be intramolecularforces (if the particles are atoms) or intermolecular forces (if the particles are molecules). When the particles are extremely close, repulsive forces startto act.

[link] summarises the characteristics of the particles that are in each phase of matter.

Table summarising the general features of solids, liquids and gases.
Property of matter Solid Liquid Gas
Particles Atoms or molecules Atoms or molecules Atoms or molecules
Energy and movement of particles Low energy - particles vibrate around a fixed point Particles have less energy than in the gas phase Particles have high energy and are constantly moving
Spaces between particles Very little space between particles. Particles are tightly packed together Smaller spaces than in gases, but larger spaces than in solids Large spaces because of high energy
Attractive forces between particles Very strong forces. Solids have a fixed volume. Stronger forces than in gas. Liquids can be poured. Weak forces because of the large distance between particles
Changes in phase Solids become liquids if their temperature is increased. In some cases a solid may become a gas if the temperature is increased. A liquid becomes a gas if its temperature is increased. It becomes a solid if its temperature decreases. In general a gas becomes a liquid when it is cooled. (In a few cases a gas becomes a solid when cooled). Particles have less energy andtherefore move closer together so that the attractive forces become stronger, and the gas becomes a liquid (or a solid.)

The following presentation is a brief summary of the above. Try to fill in the blank spaces before clicking onto the next slide.

Let's look at an example that involves the three phases of water: ice (solid), water (liquid) and water vapour(gas). Note that in the [link] below the molecules in the solid phase are represented by single spheres, but they would in reality look like the molecules in the liquid and gas phase. Sometimes werepresent molecules as single spheres in the solid phase to emphasise the small amount of space between them and to make the drawing simpler.

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Source:  OpenStax, Siyavula textbooks: grade 10 physical science [caps]. OpenStax CNX. Sep 30, 2011 Download for free at http://cnx.org/content/col11305/1.7
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