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By the end of this section, you will be able to:
  • Define corrosion
  • List some of the methods used to prevent or slow corrosion

Corrosion is usually defined as the degradation of metals due to an electrochemical process. The formation of rust on iron, tarnish on silver, and the blue-green patina that develops on copper are all examples of corrosion. The total cost of corrosion in the United States is significant, with estimates in excess of half a trillion dollars a year.

Statue of liberty: changing colors

The Statue of Liberty is a landmark every American recognizes. The Statue of Liberty is easily identified by its height, stance, and unique blue-green color ( [link] ). When this statue was first delivered from France, its appearance was not green. It was brown, the color of its copper “skin.” So how did the Statue of Liberty change colors? The change in appearance was a direct result of corrosion. The copper that is the primary component of the statue slowly underwent oxidation from the air. The oxidation-reduction reactions of copper metal in the environment occur in several steps. Copper metal is oxidized to copper(I) oxide (Cu 2 O), which is red, and then to copper(II) oxide, which is black

2Cu ( s ) + 1 2 O 2 ( g ) Cu 2 O ( s ) ( red )
Cu 2 O ( s ) + 1 2 O 2 ( g ) 2CuO ( s ) ( black )

Coal, which was often high in sulfur, was burned extensively in the early part of the last century. As a result, sulfur trioxide, carbon dioxide, and water all reacted with the CuO

2CuO ( s ) + CO 2 ( g ) + H 2 O ( l ) Cu 2 CO 3 (OH) 2 ( s ) (green)
3CuO ( s ) + 2CO 2 ( g ) + H 2 O ( l ) Cu 2 ( CO 3 ) 2 (OH) 2 ( s ) (blue)
4CuO ( s ) + SO 3 ( g ) + 3H 2 O ( l ) Cu 4 SO 4 (OH) 6 ( s ) (green)

These three compounds are responsible for the characteristic blue-green patina seen today. Fortunately, formation of the patina created a protective layer on the surface, preventing further corrosion of the copper skin. The formation of the protective layer is a form of passivation, which is discussed further in a later chapter.

This figure contains two photos of the Statue of Liberty. Photo a appears to be an antique photo which shows the original brown color of the copper covered statue. Photo b shows the blue-green appearance of the statue today. In both photos, the statue is shown atop a building, with a body of water in the background.
(a) The Statue of Liberty is covered with a copper skin, and was originally brown, as shown in this painting. (b) Exposure to the elements has resulted in the formation of the blue-green patina seen today.

Perhaps the most familiar example of corrosion is the formation of rust on iron. Iron will rust when it is exposed to oxygen and water. The main steps in the rusting of iron appear to involve the following ( [link] ). Once exposed to the atmosphere, iron rapidly oxidizes.

anode: Fe ( s ) Fe 2+ ( a q ) + 2 e E Fe 2+ /Fe ° = −0.44 V

The electrons reduce oxygen in the air in acidic solutions.

cathode: O 2 ( g ) + 4 H + ( a q ) + 4 e 2 H 2 O ( l ) E O 2 /O 2 ° = +1.23 V
overall: 2Fe ( s ) + O 2 ( g ) + 4H + ( a q ) 2 Fe 2+ ( a q ) + 2 H 2 O ( l ) E cell ° = +1.67 V

What we call rust is hydrated iron(III) oxide, which forms when iron(II) ions react further with oxygen.

4 Fe 2+ ( a q ) + O 2 ( g ) + ( 4 + 2 x ) H 2 O ( l ) 2 Fe 2 O 3 · x H 2 O ( s ) + 8 H + ( a q )

The number of water molecules is variable, so it is represented by x . Unlike the patina on copper, the formation of rust does not create a protective layer and so corrosion of the iron continues as the rust flakes off and exposes fresh iron to the atmosphere.

A grey rectangle, labeled “iron,” is shown with thin purple layers, labeled “Paint layer,” at its upper and lower surfaces. A gap in the upper purple layer at the upper left of the diagram is labeled “Cathodic site.” A blue droplet labeled “water” is positioned on top of the gap. A curved arrow extends from a space above the droplet to the surface of the grey region and into the water droplet. The base of the arrow is labeled “O subscript 2” and the tip of the arrow is labeled “H subscript 2 O.” A gap to the right and on the bottom side of the grey region shows that some of the grey region is gone from the region beneath the purple layer. A water droplet covers this gap and extends into the open space in the grey rectangle. The label “F e superscript 2 positive” is at the center of the droplet. A curved arrow points from the edge of the grey area below to the label. A second curved arrow extends from the F e superscript 2 positive arrow to a rust brown chunk on the lower surface of the purple layer at the edge of the water droplet. A curved arrow extends from O subscript 2 outside the droplet into the droplet to the rust brown chunk. The grey region at the lower right portion of the diagram is labeled “Anodic site.” An arrow extends from the anodic site toward the cathodic site, which is labeled “e superscript negative.”
Once the paint is scratched on a painted iron surface, corrosion occurs and rust begins to form. The speed of the spontaneous reaction is increased in the presence of electrolytes, such as the sodium chloride used on roads to melt ice and snow or in salt water.

Questions & Answers

what's the easiest and fastest way to the synthesize AgNP?
Damian Reply
China
Cied
types of nano material
abeetha Reply
I start with an easy one. carbon nanotubes woven into a long filament like a string
Porter
many many of nanotubes
Porter
what is the k.e before it land
Yasmin
what is the function of carbon nanotubes?
Cesar
I'm interested in nanotube
Uday
what is nanomaterials​ and their applications of sensors.
Ramkumar Reply
what is nano technology
Sravani Reply
what is system testing?
AMJAD
preparation of nanomaterial
Victor Reply
Yes, Nanotechnology has a very fast field of applications and their is always something new to do with it...
Himanshu Reply
good afternoon madam
AMJAD
what is system testing
AMJAD
what is the application of nanotechnology?
Stotaw
In this morden time nanotechnology used in many field . 1-Electronics-manufacturad IC ,RAM,MRAM,solar panel etc 2-Helth and Medical-Nanomedicine,Drug Dilivery for cancer treatment etc 3- Atomobile -MEMS, Coating on car etc. and may other field for details you can check at Google
Azam
anybody can imagine what will be happen after 100 years from now in nano tech world
Prasenjit
after 100 year this will be not nanotechnology maybe this technology name will be change . maybe aftet 100 year . we work on electron lable practically about its properties and behaviour by the different instruments
Azam
name doesn't matter , whatever it will be change... I'm taking about effect on circumstances of the microscopic world
Prasenjit
how hard could it be to apply nanotechnology against viral infections such HIV or Ebola?
Damian
silver nanoparticles could handle the job?
Damian
not now but maybe in future only AgNP maybe any other nanomaterials
Azam
Hello
Uday
I'm interested in Nanotube
Uday
this technology will not going on for the long time , so I'm thinking about femtotechnology 10^-15
Prasenjit
can nanotechnology change the direction of the face of the world
Prasenjit Reply
At high concentrations (>0.01 M), the relation between absorptivity coefficient and absorbance is no longer linear. This is due to the electrostatic interactions between the quantum dots in close proximity. If the concentration of the solution is high, another effect that is seen is the scattering of light from the large number of quantum dots. This assumption only works at low concentrations of the analyte. Presence of stray light.
Ali Reply
the Beer law works very well for dilute solutions but fails for very high concentrations. why?
bamidele Reply
how did you get the value of 2000N.What calculations are needed to arrive at it
Smarajit Reply
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razzyd Reply
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4. On the basis of dipole moments and/or hydrogen bonding, explain in a qualitative way the differences in the boiling points of acetone (56.2 °C) and 1-propanol (97.4 °C), which have similar molar masses
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Practice Key Terms 4

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Source:  OpenStax, Ut austin - principles of chemistry. OpenStax CNX. Mar 31, 2016 Download for free at http://legacy.cnx.org/content/col11830/1.13
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