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There is a relationship between the valency of an element and its position on the Periodic Table. For the elements in groups 1 to 4, the valency is thesame as the group number. For elements in groups 5 to 7, the valency is calculated by subtracting the group number from 8. For example, the valency of fluorine (group 7) is 8 - 7 = 1 , while the valency of calcium (group 2) is 2. Some elements have more than one possible valency, so you always need to be careful when you are writing a chemical formula. Often, if there is more than one possibility in terms of valency, the valency will be written in a bracket after the element symbol e.g. carbon (IV) oxide, means that in this molecule carbon has a valency of 4.

Below are a few examples. Remember that it is only the valence electrons that are involved in bonding, and so when diagrams are drawn to show what is happening during bonding, it is only these electrons that are shown. Circles and crosses are used to represent electrons in different atoms.

How do hydrogen and chlorine atoms bond covalently in a molecule of hydrogen chloride?

  1. A chlorine atom has 17 electrons, and an electron configuration of 1 s 2 2 s 2 2 p 6 3 s 2 3 p 5 . A hydrogen atom has only 1 electron, and an electron configuration of 1 s 1 .

  2. Chlorine has 7 valence electrons. One of these electrons is unpaired. Hydrogen has 1 valence electron and it is unpaired.

  3. The hydrogen atom needs one more electron to complete its valence shell. The chlorine atom also needs one more electron to complete its shell. Therefore one pair of electrons must be shared between the two atoms. In other words, one electron from the chlorine atom will spend some of its time orbiting the hydrogen atom so that hydrogen's valence shell is full. The hydrogen electron will spend some of its time orbiting the chlorine atom so that chlorine's valence shell is also full. A molecule of hydrogen chloride is formed ( [link] ). Notice the shared electron pair in the overlapping orbitals.

    Covalent bonding in a molecule of hydrogen chloride

How do nitrogen and hydrogen atoms bond to form a molecule of ammonia ( NH 3 )?

  1. A nitrogen atom has 7 electrons, and an electron configuration of 1 s 2 2 s 2 2 p 3 . A hydrogen atom has only 1 electron, and an electron configuration of 1 s 1 .

  2. Nitrogen has 5 valence electrons meaning that 3 electrons are unpaired. Hydrogen has 1 valence electron and it is unpaired.

  3. Each hydrogen atom needs one more electron to complete its valence energy shell. The nitrogen atom needs three more electrons to complete its valence energy shell. Therefore three pairs of electrons must be shared between the four atoms involved. The nitrogen atom will share three of its electrons so that each of the hydrogen atoms now have a complete valence shell. Each of the hydrogen atoms will share its electron with the nitrogen atom to complete its valence shell ( [link] ).

    Covalent bonding in a molecule of ammonia

The above examples all show single covalent bonds , where only one pair of electrons is shared between the same two atoms . If two pairs of electrons are shared between the same two atoms, this is called a double bond . A triple bond is formed if three pairs of electrons are shared.

How do oxygen atoms bond covalently to form an oxygen molecule?

  1. Each oxygen atom has 8 electrons, and their electron configuration is 1 s 2 2 s 2 2 p 4 .

  2. Each oxygen atom has 6 valence electrons, meaning that each atom has 2 unpaired electrons.

  3. Each oxygen atom needs two more electrons to complete its valence energy shell. Therefore two pairs of electrons must be shared between the two oxygen atoms so that both valence shells are full. Notice that the two electron pairs are being shared between the same two atoms, and so we call this a double bond ( [link] ).

    A double covalent bond in an oxygen molecule

Covalent bonding and valency

  1. Explain the difference between the valence electrons and the valency of an element.
  2. Complete the table below by filling in the number of valence electrons and the valency for each of the elements shown:
    Element No. of valence electrons No. of electrons needed to fill outer shell Valency
    F
    Ar
    C
    N
    O
  3. Draw simple diagrams to show how electrons are arranged in the following covalent molecules:
    1. Water ( H 2 O )
    2. Chlorine ( Cl 2 )

Properties of covalent compounds

Covalent compounds have several properties that distinguish them from ionic compounds and metals. These properties are:

  1. The melting and boiling points of covalent compounds is generally lower than that for ionic compounds.
  2. Covalent compounds are generally more flexible than ionic compounds. The molecules in covalent compounds are able to move around to some extent and can sometimes slide over each other (as is the case with graphite, this is why the lead in your pencil feels slightly slippery). In ionic compounds all the ions are tightly held in place.
  3. Covalent compounds generally are not very soluble in water.
  4. Covalent compounds generally do not conduct electricity when dissolved in water. This is because they do not dissociate as ionic compounds do.

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Source:  OpenStax, Siyavula textbooks: grade 10 physical science [caps]. OpenStax CNX. Sep 30, 2011 Download for free at http://cnx.org/content/col11305/1.7
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