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A development of the quantum mechanical concepts of bonding using valence bond and molecular orbital descriptions to account of bond strength and molecular ionization energies.


Our basis for understanding chemical bonding and the structures of molecules is the electron orbital description of the structure and valence of atoms, as provided by quantum mechanics. We assume an understanding of the periodicity of the elements based on the nuclear structure of the atom and our deductions concerning valence based on electron orbitals.


Our model of valence describes a chemical bond as resulting from the sharing of a pair of electrons in the valence shell of the bonded atoms. This sharing allows each atom to complete an octet of electrons in its valence shell, at least in the sense that we count the shared electrons as belonging to both atoms. However, it is not clear that this electron counting picture has any basis in physical reality. What is meant, more precisely, by the sharing of the electron pair in a bond, and why does this result in the bonding of two atoms together? Indeed, what does it mean to say that two atoms are bound together? Furthermore, what is the significance of sharing a pair of electrons? Why aren’t chemical bonds formed by sharing one or three electrons, for example?

We seek to understand how the details of chemical bonding are related to the properties of the molecules formed, particularly in terms of the strengths of the bonds formed.

Observation 1: bonding with a single electron

We began our analysis of the energies and motions of the electrons in atoms by observing the properties of the simplest atom, hydrogen, with a single electron. Similarly, to understand the energies and motions of electrons which lead to chemical bonding, we begin our observations with the simplest particle with a chemical bond, which is the H 2 + size 12{H rSub { size 8{2} } rSup { size 8{+{}} } } {} molecular ion. Each hydrogen nucleus has a charge of +1. An H 2 + size 12{H rSub { size 8{2} } rSup { size 8{+{}} } } {} molecular ion therefore has a single electron. It seems inconsistent with our notions of valence that a single electron, rather than an electron pair, can generate a chemical bond. However, these concepts have been based on observations on molecules, not molecular ions like H 2 + size 12{H rSub { size 8{2} } rSup { size 8{+{}} } } {} . And it is indeed found that H 2 + size 12{H rSub { size 8{2} } rSup { size 8{+{}} } } {} is a stable bound molecular ion.

What forces and motions hold the two hydrogen nuclei close together in the H 2 + size 12{H rSub { size 8{2} } rSup { size 8{+{}} } } {} ion? It is worth keeping in mind that the two nuclei must repel one another, since they are both positively charged. In the absence of the electron, the two nuclei would accelerate away from one another, rather than remaining in close proximity. What is the role of the electron? Clearly, the electron is attracted to both nuclei at the same time, and, in turn, each nucleus is attracted to the electron. The effect of this is illustrated in Fig. 1. In Fig. 1a, the electron is “outside” of the two nuclei. In this position, the electron is primarily attracted to the nucleus on the left, to which it is closer. More importantly, the nucleus on the right feels a greater repulsion from the other nucleus than attraction to the electron, which is farther away. As a result, the nucleus on the right experiences a strong force driving it away from the hydrogen atom on the left. This arrangement does not generate chemical bonding, therefore. By contrast, in Fig. 1b, the electron is between the two nuclei. In this position, the electron is roughly equally attracted to the two nuclei, and very importantly, each nucleus feels an attractive force to the electron which is greater than the repulsive force generated by the other nucleus. Focusing on the electron’s energy, the proximity of the two nuclei provides it a doubly attractive environment with a very low potential energy. If we tried to pull one of the nuclei away, this would raise the potential energy of the electron, since it would lose attraction to that nucleus. Hence, to pull one nucleus away requires us to add energy to the molecular ion. This is what is meant by a chemical bond: the energy of the electrons is lower when the atoms are in close proximity than when the atoms are far part. This “holds” the nuclei close together, since we must do work (add energy) to take the nuclei apart.

Questions & Answers

how to know photocatalytic properties of tio2 nanoparticles...what to do now
Akash Reply
it is a goid question and i want to know the answer as well
Do somebody tell me a best nano engineering book for beginners?
s. Reply
what is fullerene does it is used to make bukky balls
Devang Reply
are you nano engineer ?
what is the Synthesis, properties,and applications of carbon nano chemistry
Abhijith Reply
Mostly, they use nano carbon for electronics and for materials to be strengthened.
is Bucky paper clear?
so some one know about replacing silicon atom with phosphorous in semiconductors device?
s. Reply
Yeah, it is a pain to say the least. You basically have to heat the substarte up to around 1000 degrees celcius then pass phosphene gas over top of it, which is explosive and toxic by the way, under very low pressure.
Do you know which machine is used to that process?
how to fabricate graphene ink ?
for screen printed electrodes ?
What is lattice structure?
s. Reply
of graphene you mean?
or in general
in general
Graphene has a hexagonal structure
On having this app for quite a bit time, Haven't realised there's a chat room in it.
what is biological synthesis of nanoparticles
Sanket Reply
what's the easiest and fastest way to the synthesize AgNP?
Damian Reply
types of nano material
abeetha Reply
I start with an easy one. carbon nanotubes woven into a long filament like a string
many many of nanotubes
what is the k.e before it land
what is the function of carbon nanotubes?
I'm interested in nanotube
what is nanomaterials​ and their applications of sensors.
Ramkumar Reply
what is nano technology
Sravani Reply
what is system testing?
preparation of nanomaterial
Victor Reply
Yes, Nanotechnology has a very fast field of applications and their is always something new to do with it...
Himanshu Reply
good afternoon madam
what is system testing
what is the application of nanotechnology?
In this morden time nanotechnology used in many field . 1-Electronics-manufacturad IC ,RAM,MRAM,solar panel etc 2-Helth and Medical-Nanomedicine,Drug Dilivery for cancer treatment etc 3- Atomobile -MEMS, Coating on car etc. and may other field for details you can check at Google
anybody can imagine what will be happen after 100 years from now in nano tech world
after 100 year this will be not nanotechnology maybe this technology name will be change . maybe aftet 100 year . we work on electron lable practically about its properties and behaviour by the different instruments
name doesn't matter , whatever it will be change... I'm taking about effect on circumstances of the microscopic world
how hard could it be to apply nanotechnology against viral infections such HIV or Ebola?
silver nanoparticles could handle the job?
not now but maybe in future only AgNP maybe any other nanomaterials
I'm interested in Nanotube
this technology will not going on for the long time , so I'm thinking about femtotechnology 10^-15
can nanotechnology change the direction of the face of the world
Prasenjit Reply
how did you get the value of 2000N.What calculations are needed to arrive at it
Smarajit Reply
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Source:  OpenStax, General chemistry i. OpenStax CNX. Jul 18, 2007 Download for free at http://cnx.org/content/col10263/1.3
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