<< Chapter < Page Chapter >> Page >

Key concepts and summary

If a chemical change is carried out at constant pressure and the only work done is caused by expansion or contraction, q for the change is called the enthalpy change with the symbol Δ H , or Δ H 298 ° for reactions occurring under standard state conditions. The value of Δ H for a reaction in one direction is equal in magnitude, but opposite in sign, to Δ H for the reaction in the opposite direction, and Δ H is directly proportional to the quantity of reactants and products. Examples of enthalpy changes include enthalpy of combustion, enthalpy of fusion, enthalpy of vaporization, and standard enthalpy of formation. The standard enthalpy of formation, Δ H f ° , is the enthalpy change accompanying the formation of 1 mole of a substance from the elements in their most stable states at 1 bar (standard state). Many of the processes are carried out at 298.15 K. If the enthalpies of formation are available for the reactants and products of a reaction, the enthalpy change can be calculated using Hess’s law: If a process can be written as the sum of several stepwise processes, the enthalpy change of the total process equals the sum of the enthalpy changes of the various steps.

Key equations

  • Δ U = q + w
  • Δ H reaction ° = n × Δ H f ° (products) n × Δ H f ° ( reactants )

Chemistry end of chapter exercises

Explain how the heat measured in [link] differs from the enthalpy change for the exothermic reaction described by the following equation:
HCl ( a q ) + NaOH ( a q ) NaCl ( a q ) + H 2 O ( l )

The enthalpy change of the indicated reaction is for exactly 1 mol HCL and 1 mol NaOH; the heat in the example is produced by 0.0500 mol HCl and 0.0500 mol NaOH.

Got questions? Get instant answers now!

Using the data in the check your learning section of [link] , calculate Δ H in kJ/mol of AgNO 3 ( aq ) for the reaction: NaCl ( a q ) + AgNO 3 ( a q ) AgCl ( s ) + NaNO 3 ( a q )

Got questions? Get instant answers now!

Calculate the enthalpy of solution (Δ H for the dissolution) per mole of NH 4 NO 3 under the conditions described in [link] .

25 kJ mol −1

Got questions? Get instant answers now!

Calculate Δ H for the reaction described by the equation. ( Hint : use the value for the approximate amount of heat absorbed by the reaction that you calculated in a previous exercise.)
Ba ( OH ) 2 · 8 H 2 O ( s ) + 2 NH 4 SCN ( a q ) Ba ( SCN ) 2 ( a q ) + 2 NH 3 ( a q ) + 10 H 2 O ( l )

Got questions? Get instant answers now!

Calculate the enthalpy of solution (Δ H for the dissolution) per mole of CaCl 2 .

81 kJ mol −1

Got questions? Get instant answers now!

Although the gas used in an oxyacetylene torch ( [link] ) is essentially pure acetylene, the heat produced by combustion of one mole of acetylene in such a torch is likely not equal to the enthalpy of combustion of acetylene listed in [link] . Considering the conditions for which the tabulated data are reported, suggest an explanation.

Got questions? Get instant answers now!

How much heat is produced by burning 4.00 moles of acetylene under standard state conditions?

5204.4 kJ

Got questions? Get instant answers now!

How much heat is produced by combustion of 125 g of methanol under standard state conditions?

Got questions? Get instant answers now!

How many moles of isooctane must be burned to produce 100 kJ of heat under standard state conditions?

1.83 × 10 −2 mol

Got questions? Get instant answers now!

What mass of carbon monoxide must be burned to produce 175 kJ of heat under standard state conditions?

Got questions? Get instant answers now!

When 2.50 g of methane burns in oxygen, 125 kJ of heat is produced. What is the enthalpy of combustion per mole of methane under these conditions?

802 kJ mol −1

Got questions? Get instant answers now!

Questions & Answers

differentiate between demand and supply giving examples
Lambiv Reply
differentiated between demand and supply using examples
Lambiv
what is labour ?
Lambiv
how will I do?
Venny Reply
how is the graph works?I don't fully understand
Rezat Reply
information
Eliyee
devaluation
Eliyee
t
WARKISA
hi guys good evening to all
Lambiv
multiple choice question
Aster Reply
appreciation
Eliyee
explain perfect market
Lindiwe Reply
In economics, a perfect market refers to a theoretical construct where all participants have perfect information, goods are homogenous, there are no barriers to entry or exit, and prices are determined solely by supply and demand. It's an idealized model used for analysis,
Ezea
What is ceteris paribus?
Shukri Reply
other things being equal
AI-Robot
When MP₁ becomes negative, TP start to decline. Extuples Suppose that the short-run production function of certain cut-flower firm is given by: Q=4KL-0.6K2 - 0.112 • Where is quantity of cut flower produced, I is labour input and K is fixed capital input (K-5). Determine the average product of lab
Kelo
Extuples Suppose that the short-run production function of certain cut-flower firm is given by: Q=4KL-0.6K2 - 0.112 • Where is quantity of cut flower produced, I is labour input and K is fixed capital input (K-5). Determine the average product of labour (APL) and marginal product of labour (MPL)
Kelo
yes,thank you
Shukri
Can I ask you other question?
Shukri
what is monopoly mean?
Habtamu Reply
What is different between quantity demand and demand?
Shukri Reply
Quantity demanded refers to the specific amount of a good or service that consumers are willing and able to purchase at a give price and within a specific time period. Demand, on the other hand, is a broader concept that encompasses the entire relationship between price and quantity demanded
Ezea
ok
Shukri
how do you save a country economic situation when it's falling apart
Lilia Reply
what is the difference between economic growth and development
Fiker Reply
Economic growth as an increase in the production and consumption of goods and services within an economy.but Economic development as a broader concept that encompasses not only economic growth but also social & human well being.
Shukri
production function means
Jabir
What do you think is more important to focus on when considering inequality ?
Abdisa Reply
any question about economics?
Awais Reply
sir...I just want to ask one question... Define the term contract curve? if you are free please help me to find this answer 🙏
Asui
it is a curve that we get after connecting the pareto optimal combinations of two consumers after their mutually beneficial trade offs
Awais
thank you so much 👍 sir
Asui
In economics, the contract curve refers to the set of points in an Edgeworth box diagram where both parties involved in a trade cannot be made better off without making one of them worse off. It represents the Pareto efficient allocations of goods between two individuals or entities, where neither p
Cornelius
In economics, the contract curve refers to the set of points in an Edgeworth box diagram where both parties involved in a trade cannot be made better off without making one of them worse off. It represents the Pareto efficient allocations of goods between two individuals or entities,
Cornelius
Suppose a consumer consuming two commodities X and Y has The following utility function u=X0.4 Y0.6. If the price of the X and Y are 2 and 3 respectively and income Constraint is birr 50. A,Calculate quantities of x and y which maximize utility. B,Calculate value of Lagrange multiplier. C,Calculate quantities of X and Y consumed with a given price. D,alculate optimum level of output .
Feyisa Reply
Answer
Feyisa
c
Jabir
the market for lemon has 10 potential consumers, each having an individual demand curve p=101-10Qi, where p is price in dollar's per cup and Qi is the number of cups demanded per week by the i th consumer.Find the market demand curve using algebra. Draw an individual demand curve and the market dema
Gsbwnw Reply
suppose the production function is given by ( L, K)=L¼K¾.assuming capital is fixed find APL and MPL. consider the following short run production function:Q=6L²-0.4L³ a) find the value of L that maximizes output b)find the value of L that maximizes marginal product
Abdureman
types of unemployment
Yomi Reply
What is the difference between perfect competition and monopolistic competition?
Mohammed
Got questions? Join the online conversation and get instant answers!
Jobilize.com Reply

Get Jobilize Job Search Mobile App in your pocket Now!

Get it on Google Play Download on the App Store Now




Source:  OpenStax, Chemistry. OpenStax CNX. May 20, 2015 Download for free at http://legacy.cnx.org/content/col11760/1.9
Google Play and the Google Play logo are trademarks of Google Inc.

Notification Switch

Would you like to follow the 'Chemistry' conversation and receive update notifications?

Ask