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density = mass volume

Calculation of density

Gold—in bricks, bars, and coins—has been a form of currency for centuries. In order to swindle people into paying for a brick of gold without actually investing in a brick of gold, people have considered filling the centers of hollow gold bricks with lead to fool buyers into thinking that the entire brick is gold. It does not work: Lead is a dense substance, but its density is not as great as that of gold, 19.3 g/cm 3 . What is the density of lead if a cube of lead has an edge length of 2.00 cm and a mass of 90.7 g?

Solution

The density of a substance can be calculated by dividing its mass by its volume. The volume of a cube is calculated by cubing the edge length.

volume of lead cube = 2.00 cm × 2.00 cm × 2.00 cm = 8.00 cm 3
density = mass volume = 90.7 g 8.00 cm 3 = 11.3 g 1.00 cm 3 = 11.3 g/cm 3

(We will discuss the reason for rounding to the first decimal place in the next section.)

Check your learning

(a) To three decimal places, what is the volume of a cube (cm 3 ) with an edge length of 0.843 cm?

(b) If the cube in part (a) is copper and has a mass of 5.34 g, what is the density of copper to two decimal places?

Answer:

(a) 0.599 cm 3 ; (b) 8.91 g/cm 3

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Using displacement of water to determine density

This PhET simulation illustrates another way to determine density, using displacement of water. Determine the density of the red and yellow blocks.

Solution

When you open the density simulation and select Same Mass, you can choose from several 5.00-kg colored blocks that you can drop into a tank containing 100.00 L water. The yellow block floats (it is less dense than water), and the water level rises to 105.00 L. While floating, the yellow block displaces 5.00 L water, an amount equal to the weight of the block. The red block sinks (it is more dense than water, which has density = 1.00 kg/L), and the water level rises to 101.25 L.

The red block therefore displaces 1.25 L water, an amount equal to the volume of the block. The density of the red block is:

density = mass volume = 5.00 kg 1.25 L = 4.00 kg/L

Note that since the yellow block is not completely submerged, you cannot determine its density from this information. But if you hold the yellow block on the bottom of the tank, the water level rises to 110.00 L, which means that it now displaces 10.00 L water, and its density can be found:

density = mass volume = 5.00 kg 10.00 L = 0.500 kg/L

Check your learning

Remove all of the blocks from the water and add the green block to the tank of water, placing it approximately in the middle of the tank. Determine the density of the green block.

Answer:

2.00 kg/L

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Key concepts and summary

Measurements provide quantitative information that is critical in studying and practicing chemistry. Each measurement has an amount, a unit for comparison, and an uncertainty. Measurements can be represented in either decimal or scientific notation. Scientists primarily use the SI (International System) or metric systems. We use base SI units such as meters, seconds, and kilograms, as well as derived units, such as liters (for volume) and g/cm 3 (for density). In many cases, we find it convenient to use unit prefixes that yield fractional and multiple units, such as microseconds (10 −6 seconds) and megahertz (10 6 hertz), respectively.

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Source:  OpenStax, Chemistry. OpenStax CNX. May 20, 2015 Download for free at http://legacy.cnx.org/content/col11760/1.9
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